Optimization of Laccase/Mediator System (LMS) Stage Applied in Fractionation of Eucalyptus globulus

In a biorefinery framework, a laccase/mediator system treatment following autohydrolysis was carried out for eucalyptus wood prior to soda-anthraquinone pulping. The enzymatic and autohydrolysis conditions, with a view to maximizing the extraction of hemicelluloses while preserving the integrity of...

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Detalles Bibliográficos
Autores: Loaiza Rodríguez, Javier Mauricio, Alfaro Martínez, Ascensión, López Baldovín, Francisco, García Domínguez, María Trinidad, García Domínguez, Juan Carlos
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/16315
Acceso en línea:http://hdl.handle.net/10272/16315
Access Level:acceso abierto
Palabra clave:Autohydrolysis
Eucalyptus globulus
Laccase
Hemicellulose
Pulp
Soda-AQ
Descripción
Sumario:In a biorefinery framework, a laccase/mediator system treatment following autohydrolysis was carried out for eucalyptus wood prior to soda-anthraquinone pulping. The enzymatic and autohydrolysis conditions, with a view to maximizing the extraction of hemicelluloses while preserving the integrity of glucan, were optimized. Secondly, pulping of solid phase from Eucalyptus globulus wood autohydrolysis and the enzymatic process was carried out and compared with a conventional soda-anthraquinone (AQ) pulping process. The prehydrolysis and enzymatic delignification of the raw material prior to the delignification with soda- Anthraquinone (AQ) results in paper sheets with a lower kappa number and brightness and strength properties close to conventional soda-AQ paper and a liquid fraction rich in hemicellulose compounds that can be used in additional ways. The advantage of this biorefinery scheme is that it requires a lower concentration of chemical reagents, and lower operating times and temperature in the alkaline delignification stage, which represents an economic and environmental improvement over the conventional process.