Metastability in drowning-out crystallisation: precipitation of highly soluble sulphates
In this paper we derive equations for evaluating the supersaturation, b, and the supersaturation rate, Rb, for the drowning-out crystallisation under isothermal conditions and assuming a constant rate of the addition of the co-solvent. Such equations are applied to the drowning-out crystallisation o...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2001 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/57123 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/57123 |
| Access Level: | acceso abierto |
| Palabra clave: | 548.5 Nucleation kinetics Metastability Sulphates Drowning-out Supersaturation Cristalografía (Geología) |
| Sumario: | In this paper we derive equations for evaluating the supersaturation, b, and the supersaturation rate, Rb, for the drowning-out crystallisation under isothermal conditions and assuming a constant rate of the addition of the co-solvent. Such equations are applied to the drowning-out crystallisation of single and double sulphates in theM2SO4±LiSO4±H2O (M=Na, Rb) ternary systems. A linear relationship between lnRb and ln bmax, similar to that reported for the crystallisation by cooling, evaporation and chemical reaction, has been found. |
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