Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements

The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provide...

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Detalles Bibliográficos
Autores: Bauzá, Antonio, Alkorta, Ibon, Elguero, José, Mooibroek, Tiddo J, Frontera, Antonio
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/343013
Acceso en línea:http://hdl.handle.net/10261/343013
https://api.elsevier.com/content/abstract/scopus_id/85087843214
Access Level:acceso abierto
Palabra clave:ab initio calculations
donor-acceptor systems
non-covalent bonding
spodium bonds
supramolecular chemistry
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spelling Spodium Bonds: Noncovalent Interactions Involving Group 12 ElementsBauzá, AntonioAlkorta, IbonElguero, JoséMooibroek, Tiddo JFrontera, Antonioab initio calculationsdonor-acceptor systemsnon-covalent bondingspodium bondssupramolecular chemistryThe term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.Peer reviewed0000-0001-6876-62110000-0001-7840-2139Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242020info:eu-repo/semantics/articleartículohttp://hdl.handle.net/10261/343013https://api.elsevier.com/content/abstract/scopus_id/85087843214reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésAngewandte Chemie (International ed. in English)Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3430132026-05-22T06:33:51Z
dc.title.none.fl_str_mv Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
title Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
spellingShingle Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
Bauzá, Antonio
ab initio calculations
donor-acceptor systems
non-covalent bonding
spodium bonds
supramolecular chemistry
title_short Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
title_full Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
title_fullStr Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
title_full_unstemmed Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
title_sort Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
dc.creator.none.fl_str_mv Bauzá, Antonio
Alkorta, Ibon
Elguero, José
Mooibroek, Tiddo J
Frontera, Antonio
author Bauzá, Antonio
author_facet Bauzá, Antonio
Alkorta, Ibon
Elguero, José
Mooibroek, Tiddo J
Frontera, Antonio
author_role author
author2 Alkorta, Ibon
Elguero, José
Mooibroek, Tiddo J
Frontera, Antonio
author2_role author
author
author
author
dc.contributor.none.fl_str_mv 0000-0001-6876-6211
0000-0001-7840-2139
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv ab initio calculations
donor-acceptor systems
non-covalent bonding
spodium bonds
supramolecular chemistry
topic ab initio calculations
donor-acceptor systems
non-covalent bonding
spodium bonds
supramolecular chemistry
description The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.
publishDate 2020
dc.date.none.fl_str_mv 2020
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
artículo
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/343013
https://api.elsevier.com/content/abstract/scopus_id/85087843214
url http://hdl.handle.net/10261/343013
https://api.elsevier.com/content/abstract/scopus_id/85087843214
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Angewandte Chemie (International ed. in English)
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869405485047742464
score 15,811543

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