Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach

Chiral cyclopropyl- and cyclobutylboronic esters and -silanes have become attractive intermediates for the preparation of functionalized small rings. This review highlights the stereoselective methods developed for their preparation, including both diastereo- and enantio­selective approaches. 1 Intr...

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Detalles Bibliográficos
Autores: Martín-Heras, Víctor, Parra, Alejandro, Tortosa Manzanares, Mariola
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/680858
Acceso en línea:http://hdl.handle.net/10486/680858
https://dx.doi.org/10.1055/s-0036-1589133
Access Level:acceso abierto
Palabra clave:asymmetric synthesis
boronates
cyclobutanes
cyclopropanes
silanes
stereoselective synthesis
strained rings
Química
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spelling Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approachMartín-Heras, VíctorParra, AlejandroTortosa Manzanares, Mariolaasymmetric synthesisboronatescyclobutanescyclopropanessilanesstereoselective synthesisstrained ringsQuímicaChiral cyclopropyl- and cyclobutylboronic esters and -silanes have become attractive intermediates for the preparation of functionalized small rings. This review highlights the stereoselective methods developed for their preparation, including both diastereo- and enantio­selective approaches. 1 Introduction 2 Stereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 2.1 Diastereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 2.2 Asymmetric Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 3 ConclusionsWe thank the European Research Council (ERC-337776) and MINECO (CTQ2016-78779-R) for financial support. M.T. thanks MICINN for a RyC contractThieme PublishingDepartamento de Química OrgánicaFacultad de Ciencias20172017-12-14research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/680858https://dx.doi.org/10.1055/s-0036-1589133reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengEuropean Commission http://dx.doi.org/10.13039/501100000780 Framework Programme Seven 337776open accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6808582026-06-23T12:46:27Z
dc.title.none.fl_str_mv Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
title Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
spellingShingle Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
Martín-Heras, Víctor
asymmetric synthesis
boronates
cyclobutanes
cyclopropanes
silanes
stereoselective synthesis
strained rings
Química
title_short Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
title_full Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
title_fullStr Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
title_full_unstemmed Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
title_sort Cyclopropyl and cyclobutylboronates and silanes: A stereo­selective approach
dc.creator.none.fl_str_mv Martín-Heras, Víctor
Parra, Alejandro
Tortosa Manzanares, Mariola
author Martín-Heras, Víctor
author_facet Martín-Heras, Víctor
Parra, Alejandro
Tortosa Manzanares, Mariola
author_role author
author2 Parra, Alejandro
Tortosa Manzanares, Mariola
author2_role author
author
dc.contributor.none.fl_str_mv Departamento de Química Orgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv asymmetric synthesis
boronates
cyclobutanes
cyclopropanes
silanes
stereoselective synthesis
strained rings
Química
topic asymmetric synthesis
boronates
cyclobutanes
cyclopropanes
silanes
stereoselective synthesis
strained rings
Química
description Chiral cyclopropyl- and cyclobutylboronic esters and -silanes have become attractive intermediates for the preparation of functionalized small rings. This review highlights the stereoselective methods developed for their preparation, including both diastereo- and enantio­selective approaches. 1 Introduction 2 Stereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 2.1 Diastereoselective Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 2.2 Asymmetric Synthesis of Cyclopropyl- and Cyclobutylboronates and -silanes 3 Conclusions
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-12-14
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/680858
https://dx.doi.org/10.1055/s-0036-1589133
url http://hdl.handle.net/10486/680858
https://dx.doi.org/10.1055/s-0036-1589133
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://dx.doi.org/10.13039/501100000780 Framework Programme Seven 337776
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Thieme Publishing
publisher.none.fl_str_mv Thieme Publishing
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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