Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons

The rational design of heterometallic compounds bearing s-block metal ions have been a difficult task for chemists owing to their lack of preferential geometries. However, some strategies, such as the design of coordinating pockets with different sizes and/or donor atoms, have offered great results....

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Authors: Ejarque, Daniel|||0000-0002-1014-1128, Calvet, Teresa|||0000-0002-4058-7171, Font-Bardia, M., Pons Picart, Josefina|||0000-0003-1834-9326
Format: article
Publication Date:2022
Country:España
Institution:Universitat Autònoma de Barcelona
Repository:Dipòsit Digital de Documents de la UAB
Language:English
OAI Identifier:oai:ddd.uab.cat:265189
Online Access:https://ddd.uab.cat/record/265189
https://dx.doi.org/urn:doi:10.3390/inorganics10080118
Access Level:Open access
Keyword:Heterometallic complexes
Trinuclear complexes
Zn(II)
Ca(II)
Secondary building unit
X-ray crystal structure
α-acetamidocinnamic acid
Solid-state photoluminescence
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spelling Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide SynthonsEjarque, Daniel|||0000-0002-1014-1128Calvet, Teresa|||0000-0002-4058-7171Font-Bardia, M.Pons Picart, Josefina|||0000-0003-1834-9326Heterometallic complexesTrinuclear complexesZn(II)Ca(II)Secondary building unitX-ray crystal structureα-acetamidocinnamic acidSolid-state photoluminescenceThe rational design of heterometallic compounds bearing s-block metal ions have been a difficult task for chemists owing to their lack of preferential geometries. However, some strategies, such as the design of coordinating pockets with different sizes and/or donor atoms, have offered great results. In this work, this strategy has been tested using Ca(II) as an s-block metal ion and a compound previously obtained by our group with the formula [Zn(μ-ACA)(4-phpy)], which contains tetrahedral N,O- and octahedral O-coordinating pockets as a model structure. From this work, the corresponding heterometallic compound with the formula [ZnCa(μ-ACA)(4-phpy)]·EtOH (1) has been successfully synthesized, and fully characterized, and its crystal structure has been elucidated. Furthermore, we have compiled all the crystal structures containing [ZnM] pinwheel secondary building units (SBUs), where M stands for an s-block metal ion, and the observed tendencies, as well as the promising applications as template SBUs for the preparation of 1D-3D coordination polymers, have been discussed. Finally, solid-state UV-Vis and photoluminescence have been recorded and compared with the homometallic [Zn(μ-ACA)(4-phpy)] compound. 22022-01-0120222022-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/265189https://dx.doi.org/urn:doi:10.3390/inorganics10080118reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaIngléseng"la Caixa" Foundation https://doi.org/10.13039/100010434 CB615921"la Caixa" Foundation https://doi.org/10.13039/100010434 CB616406Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-1687open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2651892026-06-06T12:50:31Z
dc.title.none.fl_str_mv Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
title Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
spellingShingle Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
Ejarque, Daniel|||0000-0002-1014-1128
Heterometallic complexes
Trinuclear complexes
Zn(II)
Ca(II)
Secondary building unit
X-ray crystal structure
α-acetamidocinnamic acid
Solid-state photoluminescence
title_short Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
title_full Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
title_fullStr Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
title_full_unstemmed Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
title_sort Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons
dc.creator.none.fl_str_mv Ejarque, Daniel|||0000-0002-1014-1128
Calvet, Teresa|||0000-0002-4058-7171
Font-Bardia, M.
Pons Picart, Josefina|||0000-0003-1834-9326
author Ejarque, Daniel|||0000-0002-1014-1128
author_facet Ejarque, Daniel|||0000-0002-1014-1128
Calvet, Teresa|||0000-0002-4058-7171
Font-Bardia, M.
Pons Picart, Josefina|||0000-0003-1834-9326
author_role author
author2 Calvet, Teresa|||0000-0002-4058-7171
Font-Bardia, M.
Pons Picart, Josefina|||0000-0003-1834-9326
author2_role author
author
author
dc.subject.none.fl_str_mv Heterometallic complexes
Trinuclear complexes
Zn(II)
Ca(II)
Secondary building unit
X-ray crystal structure
α-acetamidocinnamic acid
Solid-state photoluminescence
topic Heterometallic complexes
Trinuclear complexes
Zn(II)
Ca(II)
Secondary building unit
X-ray crystal structure
α-acetamidocinnamic acid
Solid-state photoluminescence
description The rational design of heterometallic compounds bearing s-block metal ions have been a difficult task for chemists owing to their lack of preferential geometries. However, some strategies, such as the design of coordinating pockets with different sizes and/or donor atoms, have offered great results. In this work, this strategy has been tested using Ca(II) as an s-block metal ion and a compound previously obtained by our group with the formula [Zn(μ-ACA)(4-phpy)], which contains tetrahedral N,O- and octahedral O-coordinating pockets as a model structure. From this work, the corresponding heterometallic compound with the formula [ZnCa(μ-ACA)(4-phpy)]·EtOH (1) has been successfully synthesized, and fully characterized, and its crystal structure has been elucidated. Furthermore, we have compiled all the crystal structures containing [ZnM] pinwheel secondary building units (SBUs), where M stands for an s-block metal ion, and the observed tendencies, as well as the promising applications as template SBUs for the preparation of 1D-3D coordination polymers, have been discussed. Finally, solid-state UV-Vis and photoluminescence have been recorded and compared with the homometallic [Zn(μ-ACA)(4-phpy)] compound.
publishDate 2022
dc.date.none.fl_str_mv 2
2022-01-01
2022
2022-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/265189
https://dx.doi.org/urn:doi:10.3390/inorganics10080118
url https://ddd.uab.cat/record/265189
https://dx.doi.org/urn:doi:10.3390/inorganics10080118
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv "la Caixa" Foundation https://doi.org/10.13039/100010434 CB615921
"la Caixa" Foundation https://doi.org/10.13039/100010434 CB616406
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-1687
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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