Solventless crosslinking of chitosan, xanthan, and locust bean gum networks functionalized with beta-Cyclodextrin

The incorporation of cyclodextrins into polymeric crosslinked gels of hydrophilic nature can be useful for promoting the sorption of hydrophobic molecules and/or modulating the release of active principles. The covalent addition of these excipients to the matrix integrates their solubilizing effect...

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Detalles Bibliográficos
Autores: Petitjean, M. (Max)|||/items/9fb66a52-1aa9-41fa-9443-8c527a99646c, Aussant, F. (Florian)|||/items/d9a8185d-ac1f-4a10-828b-df66b10b6197, Vergara, A. (Ainara)|||/items/7233c554-13cc-497f-a48a-e58760dbd6ee, Isasi-Allica, J.R. (José Ramón)|||/items/75140f94-5739-4e6a-b40c-be14e579a64c
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad de Navarra
Repositorio:Dadun. Depósito Académico Digital de la Universidad de Navarra
Idioma:inglés
OAI Identifier:oai:dadun.unav.edu:10171/67897
Acceso en línea:https://hdl.handle.net/10171/67897
Access Level:acceso abierto
Palabra clave:Cyclodextrin polymers
Chitosan
Xanthan gum
Locust bean gum
Green synthesis
Sorption
Hydrogels
Descripción
Sumario:The incorporation of cyclodextrins into polymeric crosslinked gels of hydrophilic nature can be useful for promoting the sorption of hydrophobic molecules and/or modulating the release of active principles. The covalent addition of these excipients to the matrix integrates their solubilizing effect that can contribute to increase the capacity of retention of hydrophobic substances. In this study, three diverse polysaccharides, chitosan, xanthan gum, and locust bean gum, were crosslinked with or withoutβ-cyclodextrin, using citric acid in different ratios, to create hydrogel matrices. Through a green synthetic path, the efficient production of soluble and insoluble (hydrogel) networks functionalized with β-cyclodextrin was achieved by means of a solventless procedure. The characterization of their chemical composition, swelling in water, and their sorption and release behavior were also carried out in this work.