Octahedral Molybdenum Cluster-Based Single Crystals as Fabry–Pérot Microresonators

Single crystals built up from octahedral Mo6 cluster units, with appropriate geometry and size, constitute Fabry–Pérot-type optical microcavities with well-defined resonances. Such resonances appear in the VIS-NIR range when performing optical transmittance (OT) or photoluminescence (PL) measurement...

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Detalles Bibliográficos
Autores: Segura-Sanchis, Elena, Fenollosa, Roberto, Rodríguez, Isabelle, Molard, Yann, Cordier, Stéphane, Feliz Rodríguez, Marta, Atienzar, Pedro
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/273013
Acceso en línea:http://hdl.handle.net/10261/273013
Access Level:acceso abierto
Descripción
Sumario:Single crystals built up from octahedral Mo6 cluster units, with appropriate geometry and size, constitute Fabry–Pérot-type optical microcavities with well-defined resonances. Such resonances appear in the VIS-NIR range when performing optical transmittance (OT) or photoluminescence (PL) measurements. They strongly depend on the crystal thickness and on the optical constants of the material, specifically the real and imaginary parts of the refractive index. In this work, the accurate measurement of the crystal thickness is used for the determination of the optical constants by means of a fitting process, and the preferred orientation of the crystals was determined by X-ray diffraction.