Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens

[EN] Cellulose, hemicellulose, and lignin are the main constituents of lignocellulose nanofibrils (LCNFs). The content and modification of lignin in the pulps affect the production process and characteristics of LCNFs, showing changes in their morphology, surface, rheological, and dielectric behavio...

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Autores: Albornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976X, Teruel-Juanes, Roberto|||0000-0002-0190-4445, Ribes-Greus, A.|||0000-0003-2460-8291, Ortega-Sanhueza, Isidora, Henríquez-Gallegos, Sergio, Pereira, Miguel
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/209787
Acceso en línea:https://riunet.upv.es/handle/10251/209787
Access Level:acceso abierto
Palabra clave:Eucalyptus nitens
Lignocellulose nanofibers
Morphology
Rheology
Dielectric properties
MAQUINAS Y MOTORES TERMICOS
TECNOLOGIA ELECTRONICA
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spelling Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitensAlbornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976XTeruel-Juanes, Roberto|||0000-0002-0190-4445Ribes-Greus, A.|||0000-0003-2460-8291Ortega-Sanhueza, IsidoraHenríquez-Gallegos, SergioPereira, MiguelEucalyptus nitensLignocellulose nanofibersMorphologyRheologyDielectric propertiesMAQUINAS Y MOTORES TERMICOSTECNOLOGIA ELECTRONICA[EN] Cellulose, hemicellulose, and lignin are the main constituents of lignocellulose nanofibrils (LCNFs). The content and modification of lignin in the pulps affect the production process and characteristics of LCNFs, showing changes in their morphology, surface, rheological, and dielectric behaviors. Due to controversy and relevance in applications, these changes still need to be explained. This work seeks to understand the effect of lignin content and its oxidation on the production process and the characteristics of LCNFs. It was possible to produce pulps with fibers of similar physical characteristics and carbohydrate content after delignification, allowing the identification of the isolated effects of in situ lignin. A lower amount of lignin facilitated the LCNF production process, generating fibrils with smaller widths (up to similar to 48%) but more considerable apparent lengths (up to similar to 73%). In addition, the viscosity of the suspensions increased for LCNFs with lower lignin content (up to similar to 3.5 times to 0.5% (w/v)), due to increased flexibility, specific surface area, and surface charge of the fibrils. Finally, the LCNFs showed four dipolar relaxations, where the glass transition temperature of lignin decreased with oxidation and increased with increasing condensed structures and decreasing S/G ratio.This work was funded by the Agencia Nacional de Investigacion y Desarrollo (ANID)/Doctorado Nacional/2018-21181080, and projects FONDECYT N degrees 1201042, CORFO Grant no. 13CEI2-21839, and INNOMAT-H2 (MFA/2022/041) (Conselleria d'Innovacio, Universitats, Ciencia i Societat Digital).Springer-VerlagDepartamento de Ingeniería ElectrónicaDepartamento de Máquinas y Motores TérmicosEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialDepartamento de Ingeniería EléctricaEscuela Técnica Superior de Ingeniería Industrial Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyGENERALITAT VALENCIANACorporación de Fomento de la Producción, ChileAgencia Nacional de Investigación y Desarrollo de ChileFondo Nacional de Desarrollo Científico y Tecnológico, ChileRepositorio Institucional de la Universitat Politècnica de València Riunet20232023-07-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/209787reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengGeneralitat Valenciana https://doi.org/10.13039/501100003359 Programa Materiales con Funcionalidades Avanzadas para la Nueva Transformación Tecnológica MFA%2F2022%2F041 Diseño y validación de materiales innovadores para su desarrollo como electrolitos de pilas de combustible de intercambio protónico en vehículosFondo Nacional de Desarrollo Científico y Tecnológico, Chile https://doi.org/10.13039/501100002850 1201042Corporación de Fomento de la Producción, Chile https://doi.org/10.13039/100009465 13CEI2-21839Agencia Nacional de Investigación y Desarrollo, Chile ANID 21181080open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2097872026-06-13T07:49:27Z
dc.title.none.fl_str_mv Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
title Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
spellingShingle Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
Albornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976X
Eucalyptus nitens
Lignocellulose nanofibers
Morphology
Rheology
Dielectric properties
MAQUINAS Y MOTORES TERMICOS
TECNOLOGIA ELECTRONICA
title_short Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
title_full Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
title_fullStr Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
title_full_unstemmed Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
title_sort Understanding the effect of lignin on the production process and characteristics of lignocellulose nanofibrils from Eucalyptus nitens
dc.creator.none.fl_str_mv Albornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976X
Teruel-Juanes, Roberto|||0000-0002-0190-4445
Ribes-Greus, A.|||0000-0003-2460-8291
Ortega-Sanhueza, Isidora
Henríquez-Gallegos, Sergio
Pereira, Miguel
author Albornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976X
author_facet Albornoz-Palma, Gregory Piero Horacio|||0000-0002-1194-976X
Teruel-Juanes, Roberto|||0000-0002-0190-4445
Ribes-Greus, A.|||0000-0003-2460-8291
Ortega-Sanhueza, Isidora
Henríquez-Gallegos, Sergio
Pereira, Miguel
author_role author
author2 Teruel-Juanes, Roberto|||0000-0002-0190-4445
Ribes-Greus, A.|||0000-0003-2460-8291
Ortega-Sanhueza, Isidora
Henríquez-Gallegos, Sergio
Pereira, Miguel
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Electrónica
Departamento de Máquinas y Motores Térmicos
Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial
Departamento de Ingeniería Eléctrica
Escuela Técnica Superior de Ingeniería Industrial
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
GENERALITAT VALENCIANA
Corporación de Fomento de la Producción, Chile
Agencia Nacional de Investigación y Desarrollo de Chile
Fondo Nacional de Desarrollo Científico y Tecnológico, Chile
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Eucalyptus nitens
Lignocellulose nanofibers
Morphology
Rheology
Dielectric properties
MAQUINAS Y MOTORES TERMICOS
TECNOLOGIA ELECTRONICA
topic Eucalyptus nitens
Lignocellulose nanofibers
Morphology
Rheology
Dielectric properties
MAQUINAS Y MOTORES TERMICOS
TECNOLOGIA ELECTRONICA
description [EN] Cellulose, hemicellulose, and lignin are the main constituents of lignocellulose nanofibrils (LCNFs). The content and modification of lignin in the pulps affect the production process and characteristics of LCNFs, showing changes in their morphology, surface, rheological, and dielectric behaviors. Due to controversy and relevance in applications, these changes still need to be explained. This work seeks to understand the effect of lignin content and its oxidation on the production process and the characteristics of LCNFs. It was possible to produce pulps with fibers of similar physical characteristics and carbohydrate content after delignification, allowing the identification of the isolated effects of in situ lignin. A lower amount of lignin facilitated the LCNF production process, generating fibrils with smaller widths (up to similar to 48%) but more considerable apparent lengths (up to similar to 73%). In addition, the viscosity of the suspensions increased for LCNFs with lower lignin content (up to similar to 3.5 times to 0.5% (w/v)), due to increased flexibility, specific surface area, and surface charge of the fibrils. Finally, the LCNFs showed four dipolar relaxations, where the glass transition temperature of lignin decreased with oxidation and increased with increasing condensed structures and decreasing S/G ratio.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-07-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/209787
url https://riunet.upv.es/handle/10251/209787
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Generalitat Valenciana https://doi.org/10.13039/501100003359 Programa Materiales con Funcionalidades Avanzadas para la Nueva Transformación Tecnológica MFA%2F2022%2F041 Diseño y validación de materiales innovadores para su desarrollo como electrolitos de pilas de combustible de intercambio protónico en vehículos
Fondo Nacional de Desarrollo Científico y Tecnológico, Chile https://doi.org/10.13039/501100002850 1201042
Corporación de Fomento de la Producción, Chile https://doi.org/10.13039/100009465 13CEI2-21839
Agencia Nacional de Investigación y Desarrollo, Chile ANID 21181080
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer-Verlag
publisher.none.fl_str_mv Springer-Verlag
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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