Near-commensuration from intertwined charge density waves in single-layer TiSe2

When the period of an incommensurate charge density wave (ICDW) approaches a multiple of a lattice vector, the energy gain from locking the period can drive a transition into an intermediate near-commensurate (NC) state made of locally commensurate regions separated by phase slips of a complex CDW....

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Bibliographic Details
Authors: Wan, Wen, Gastiasoro, Maria N., Muñoz-Segovia, Daniel, Dreher, Paul, Ugeda, Miguel M., Juan, Fernando de
Format: article
Status:Published version
Publication Date:2026
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/424624
Online Access:http://hdl.handle.net/10261/424624
Access Level:Open access
Keyword:Near commensurate charge density waves
Scanning tunneling microscopy
2D materials
Transition metal dichalcogenides
Description
Summary:When the period of an incommensurate charge density wave (ICDW) approaches a multiple of a lattice vector, the energy gain from locking the period can drive a transition into an intermediate near-commensurate (NC) state made of locally commensurate regions separated by phase slips of a complex CDW. In TiSe2, a paradigmatic CDW system, incommensuration is believed to be induced by carrier doping, yet its putative NC state has never been imaged. Here we observe a striking NC state in ultraclean, doped monolayers of TiSe2, displaying an intricate network of unidirectional domain walls. Detailed analysis reveals that these are not phase slips of a complex CDW, but rather sign-changing Ising-type domain walls of two coupled real CDWs of different symmetry. In addition, these CDWs are coupled to an unexpected nematic modulation at the lattice Bragg peaks. TiSe2 is thus a rare example of a NC-CDW of two intertwined real modulations with nematicity.