Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres

Flexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation...

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Detalles Bibliográficos
Autores: García Torres, José Manuel|||0000-0002-3996-0274, Crean, Carol
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/121366
Acceso en línea:https://hdl.handle.net/2117/121366
https://dx.doi.org/10.1016/j.matdes.2018.05.070
Access Level:acceso abierto
Palabra clave:Carbon nanotubes
Manganese oxides
Energy storage
Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage
Nanotubs de carboni
Manganès -- Oxidació
Energia -- Emmagatzematge
Àrees temàtiques de la UPC::Enginyeria dels materials
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spelling Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibresGarcía Torres, José Manuel|||0000-0002-3996-0274Crean, CarolCarbon nanotubesManganese oxidesEnergy storageFibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storageNanotubs de carboniManganès -- OxidacióEnergia -- EmmagatzematgeÀrees temàtiques de la UPC::Enginyeria dels materialsFlexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation creates a simple solutionbased continuous process to produce fibre-based energy storage. Well-controlled depositions were achieved and have been optimised at each stage to yield the highest specific capacitance. A single ternary composite fibre exhibited a specific capacitance of 351 F g-1. Two ternary composite fibre electrodes were assembled together in a parallel solid-state device, with polyvinyl alcohol/H3PO4 gel used as both an electrolyte and a separator. The assembled flexible device exhibited a high specific capacitance of 51.3 F g-1 with excellent both chargedischarge cycling (84.2% capacitance retention after 1000 cycles) and deformation cycling stability (82.1% capacitance retention after 1000 bending cycles).Peer ReviewedElsevier20182018-10-0520182018-09-21journal articlehttp://purl.org/coar/resource_type/c_6501AOhttp://purl.org/coar/version/c_b1a7d7d4d402bcceinfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/121366https://dx.doi.org/10.1016/j.matdes.2018.05.070reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivs 3.0 Spainhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/1213662026-05-27T15:37:01Z
dc.title.none.fl_str_mv Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
title Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
spellingShingle Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
García Torres, José Manuel|||0000-0002-3996-0274
Carbon nanotubes
Manganese oxides
Energy storage
Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage
Nanotubs de carboni
Manganès -- Oxidació
Energia -- Emmagatzematge
Àrees temàtiques de la UPC::Enginyeria dels materials
title_short Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
title_full Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
title_fullStr Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
title_full_unstemmed Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
title_sort Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
dc.creator.none.fl_str_mv García Torres, José Manuel|||0000-0002-3996-0274
Crean, Carol
author García Torres, José Manuel|||0000-0002-3996-0274
author_facet García Torres, José Manuel|||0000-0002-3996-0274
Crean, Carol
author_role author
author2 Crean, Carol
author2_role author
dc.subject.none.fl_str_mv Carbon nanotubes
Manganese oxides
Energy storage
Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage
Nanotubs de carboni
Manganès -- Oxidació
Energia -- Emmagatzematge
Àrees temàtiques de la UPC::Enginyeria dels materials
topic Carbon nanotubes
Manganese oxides
Energy storage
Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage
Nanotubs de carboni
Manganès -- Oxidació
Energia -- Emmagatzematge
Àrees temàtiques de la UPC::Enginyeria dels materials
description Flexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation creates a simple solutionbased continuous process to produce fibre-based energy storage. Well-controlled depositions were achieved and have been optimised at each stage to yield the highest specific capacitance. A single ternary composite fibre exhibited a specific capacitance of 351 F g-1. Two ternary composite fibre electrodes were assembled together in a parallel solid-state device, with polyvinyl alcohol/H3PO4 gel used as both an electrolyte and a separator. The assembled flexible device exhibited a high specific capacitance of 51.3 F g-1 with excellent both chargedischarge cycling (84.2% capacitance retention after 1000 cycles) and deformation cycling stability (82.1% capacitance retention after 1000 bending cycles).
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-10-05
2018
2018-09-21
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AO
http://purl.org/coar/version/c_b1a7d7d4d402bcce
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/121366
https://dx.doi.org/10.1016/j.matdes.2018.05.070
url https://hdl.handle.net/2117/121366
https://dx.doi.org/10.1016/j.matdes.2018.05.070
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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