Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres
Flexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation...
| Autores: | , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/121366 |
| Acceso en línea: | https://hdl.handle.net/2117/121366 https://dx.doi.org/10.1016/j.matdes.2018.05.070 |
| Access Level: | acceso abierto |
| Palabra clave: | Carbon nanotubes Manganese oxides Energy storage Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage Nanotubs de carboni Manganès -- Oxidació Energia -- Emmagatzematge Àrees temàtiques de la UPC::Enginyeria dels materials |
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Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibresGarcía Torres, José Manuel|||0000-0002-3996-0274Crean, CarolCarbon nanotubesManganese oxidesEnergy storageFibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storageNanotubs de carboniManganès -- OxidacióEnergia -- EmmagatzematgeÀrees temàtiques de la UPC::Enginyeria dels materialsFlexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation creates a simple solutionbased continuous process to produce fibre-based energy storage. Well-controlled depositions were achieved and have been optimised at each stage to yield the highest specific capacitance. A single ternary composite fibre exhibited a specific capacitance of 351 F g-1. Two ternary composite fibre electrodes were assembled together in a parallel solid-state device, with polyvinyl alcohol/H3PO4 gel used as both an electrolyte and a separator. The assembled flexible device exhibited a high specific capacitance of 51.3 F g-1 with excellent both chargedischarge cycling (84.2% capacitance retention after 1000 cycles) and deformation cycling stability (82.1% capacitance retention after 1000 bending cycles).Peer ReviewedElsevier20182018-10-0520182018-09-21journal articlehttp://purl.org/coar/resource_type/c_6501AOhttp://purl.org/coar/version/c_b1a7d7d4d402bcceinfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/121366https://dx.doi.org/10.1016/j.matdes.2018.05.070reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivs 3.0 Spainhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/1213662026-05-27T15:37:01Z |
| dc.title.none.fl_str_mv |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| title |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| spellingShingle |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres García Torres, José Manuel|||0000-0002-3996-0274 Carbon nanotubes Manganese oxides Energy storage Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage Nanotubs de carboni Manganès -- Oxidació Energia -- Emmagatzematge Àrees temàtiques de la UPC::Enginyeria dels materials |
| title_short |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| title_full |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| title_fullStr |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| title_full_unstemmed |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| title_sort |
Ternary composite solid-state flexible supercapacitor based on nanocarbons/manganese dioxide/PEDOT:PSS fibres |
| dc.creator.none.fl_str_mv |
García Torres, José Manuel|||0000-0002-3996-0274 Crean, Carol |
| author |
García Torres, José Manuel|||0000-0002-3996-0274 |
| author_facet |
García Torres, José Manuel|||0000-0002-3996-0274 Crean, Carol |
| author_role |
author |
| author2 |
Crean, Carol |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Carbon nanotubes Manganese oxides Energy storage Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage Nanotubs de carboni Manganès -- Oxidació Energia -- Emmagatzematge Àrees temàtiques de la UPC::Enginyeria dels materials |
| topic |
Carbon nanotubes Manganese oxides Energy storage Fibre supercapacitor Carbon nanotube Wet-spinning Manganese oxides PEDOT:PSS Energy storage Nanotubs de carboni Manganès -- Oxidació Energia -- Emmagatzematge Àrees temàtiques de la UPC::Enginyeria dels materials |
| description |
Flexible fibre supercapacitors were fabricated by wet-spinning from carbon nanotube/carbon black dispersions, followed by straightforward surface treatments to sequentially deposit MnO2 and PEDOT:PSS to make ternary composite fibres. Dip coating the fibres after the initial wet-spinning coagulation creates a simple solutionbased continuous process to produce fibre-based energy storage. Well-controlled depositions were achieved and have been optimised at each stage to yield the highest specific capacitance. A single ternary composite fibre exhibited a specific capacitance of 351 F g-1. Two ternary composite fibre electrodes were assembled together in a parallel solid-state device, with polyvinyl alcohol/H3PO4 gel used as both an electrolyte and a separator. The assembled flexible device exhibited a high specific capacitance of 51.3 F g-1 with excellent both chargedischarge cycling (84.2% capacitance retention after 1000 cycles) and deformation cycling stability (82.1% capacitance retention after 1000 bending cycles). |
| publishDate |
2018 |
| dc.date.none.fl_str_mv |
2018 2018-10-05 2018 2018-09-21 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 AO http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/2117/121366 https://dx.doi.org/10.1016/j.matdes.2018.05.070 |
| url |
https://hdl.handle.net/2117/121366 https://dx.doi.org/10.1016/j.matdes.2018.05.070 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:UPCommons. Portal del coneixement obert de la UPC instname:Universitat Politècnica de Catalunya (UPC) |
| instname_str |
Universitat Politècnica de Catalunya (UPC) |
| reponame_str |
UPCommons. Portal del coneixement obert de la UPC |
| collection |
UPCommons. Portal del coneixement obert de la UPC |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
|
| _version_ |
1869405055355977728 |
| score |
15.301603 |