Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones

[EN]A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or a catalytic amount of the TiIII reagent. The...

ver descrição completa

Detalhes bibliográficos
Autores: Fernández Mateos, Alfonso, Encinas Madrazo, Soledad, Herrero Teijón, Pablo, Rubio González, María Rosa
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Recursos:Universidad de Salamanca (USAL)
Repositorio:GREDOS. Repositorio Institucional de la Universidad de Salamanca
OAI Identifier:oai:gredos.usal.es:10366/154211
Acesso em linha:http://hdl.handle.net/10366/154211
Access Level:acceso abierto
Palavra-chave:Synthetic methods
Radicals
Titanium
Cross-coupling
Epoxides
Vinyl sulfones
2306 Química Orgánica
id ES_2a23ac452e65bb5caac5ca8b30d4c7c5
oai_identifier_str oai:gredos.usal.es:10366/154211
network_acronym_str ES
network_name_str España
repository_id_str
spelling Radical Titanocene Promoted Coupling of Epoxides and Vinyl SulfonesFernández Mateos, AlfonsoEncinas Madrazo, SoledadHerrero Teijón, PabloRubio González, María RosaSynthetic methodsRadicalsTitaniumCross-couplingEpoxidesVinyl sulfones2306 Química Orgánica[EN]A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or a catalytic amount of the TiIII reagent. The scope of the reaction was studied for several different functionalized and substituted epoxides and vinyl sulfones.202420242015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10366/154211reponame:GREDOS. Repositorio Institucional de la Universidad de Salamancainstname:Universidad de Salamanca (USAL)InglésAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:gredos.usal.es:10366/1542112026-06-07T06:28:51Z
dc.title.none.fl_str_mv Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
title Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
spellingShingle Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
Fernández Mateos, Alfonso
Synthetic methods
Radicals
Titanium
Cross-coupling
Epoxides
Vinyl sulfones
2306 Química Orgánica
title_short Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
title_full Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
title_fullStr Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
title_full_unstemmed Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
title_sort Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones
dc.creator.none.fl_str_mv Fernández Mateos, Alfonso
Encinas Madrazo, Soledad
Herrero Teijón, Pablo
Rubio González, María Rosa
author Fernández Mateos, Alfonso
author_facet Fernández Mateos, Alfonso
Encinas Madrazo, Soledad
Herrero Teijón, Pablo
Rubio González, María Rosa
author_role author
author2 Encinas Madrazo, Soledad
Herrero Teijón, Pablo
Rubio González, María Rosa
author2_role author
author
author
dc.subject.none.fl_str_mv Synthetic methods
Radicals
Titanium
Cross-coupling
Epoxides
Vinyl sulfones
2306 Química Orgánica
topic Synthetic methods
Radicals
Titanium
Cross-coupling
Epoxides
Vinyl sulfones
2306 Química Orgánica
description [EN]A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or a catalytic amount of the TiIII reagent. The scope of the reaction was studied for several different functionalized and substituted epoxides and vinyl sulfones.
publishDate 2015
dc.date.none.fl_str_mv 2015
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10366/154211
url http://hdl.handle.net/10366/154211
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:GREDOS. Repositorio Institucional de la Universidad de Salamanca
instname:Universidad de Salamanca (USAL)
instname_str Universidad de Salamanca (USAL)
reponame_str GREDOS. Repositorio Institucional de la Universidad de Salamanca
collection GREDOS. Repositorio Institucional de la Universidad de Salamanca
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869405050889043968
score 15,301603

Registos relacionados