Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone

In an attempt to evaluate the separation of certain impurities that arise in some stages of the production of cyclohexanone, this work analyzed the possibility of removing five of these substances via rectification. Due to the scarcity of experimental vapor–liquid equilibrium data for most of the so...

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Detalles Bibliográficos
Autores: Sosa, Adriel, Ortega, Juan, Fernández, Luis, Romero, Arturo, Santos López, Aurora, Lorenzo Fernández, David
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/72304
Acceso en línea:https://hdl.handle.net/20.500.14352/72304
Access Level:acceso abierto
Palabra clave:66.0
Cyclohexanone
Vapor–liquid equilibrium
UNIFAC
COSMO-RS
distillation
Ingeniería química
3303 Ingeniería y Tecnología Químicas
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oai_identifier_str oai:docta.ucm.es:20.500.14352/72304
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repository_id_str
spelling Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of CyclohexanoneSosa, AdrielOrtega, JuanFernández, LuisRomero, ArturoSantos López, AuroraLorenzo Fernández, David66.0CyclohexanoneVapor–liquid equilibriumUNIFACCOSMO-RSdistillationIngeniería química3303 Ingeniería y Tecnología QuímicasIn an attempt to evaluate the separation of certain impurities that arise in some stages of the production of cyclohexanone, this work analyzed the possibility of removing five of these substances via rectification. Due to the scarcity of experimental vapor–liquid equilibrium data for most of the solutions in the effluent of the global process, prior knowledge of their behavior is required. In this work, two predictive models, UNIFAC and COSMO-RS, were used to determine a priori the possibility of obtaining, by distillation, the individual components of seven of the binaries formed by the combination of these five compounds. Since both procedures described quasi-ideal behavior for all the chosen solutions, the results are considered as an approximation, owing to the special nature of the studied systems. The results and characteristics of each system are discussed separately.MDPIUniversidad Complutense de Madrid20222022-01-0120222022-01-01journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/72304reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución 3.0 Españahttps://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/723042026-06-02T12:44:21Z
dc.title.none.fl_str_mv Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
title Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
spellingShingle Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
Sosa, Adriel
66.0
Cyclohexanone
Vapor–liquid equilibrium
UNIFAC
COSMO-RS
distillation
Ingeniería química
3303 Ingeniería y Tecnología Químicas
title_short Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
title_full Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
title_fullStr Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
title_full_unstemmed Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
title_sort Evaluation of VLEs for Binaries of Five Compounds Involved in the Production Processes of Cyclohexanone
dc.creator.none.fl_str_mv Sosa, Adriel
Ortega, Juan
Fernández, Luis
Romero, Arturo
Santos López, Aurora
Lorenzo Fernández, David
author Sosa, Adriel
author_facet Sosa, Adriel
Ortega, Juan
Fernández, Luis
Romero, Arturo
Santos López, Aurora
Lorenzo Fernández, David
author_role author
author2 Ortega, Juan
Fernández, Luis
Romero, Arturo
Santos López, Aurora
Lorenzo Fernández, David
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 66.0
Cyclohexanone
Vapor–liquid equilibrium
UNIFAC
COSMO-RS
distillation
Ingeniería química
3303 Ingeniería y Tecnología Químicas
topic 66.0
Cyclohexanone
Vapor–liquid equilibrium
UNIFAC
COSMO-RS
distillation
Ingeniería química
3303 Ingeniería y Tecnología Químicas
description In an attempt to evaluate the separation of certain impurities that arise in some stages of the production of cyclohexanone, this work analyzed the possibility of removing five of these substances via rectification. Due to the scarcity of experimental vapor–liquid equilibrium data for most of the solutions in the effluent of the global process, prior knowledge of their behavior is required. In this work, two predictive models, UNIFAC and COSMO-RS, were used to determine a priori the possibility of obtaining, by distillation, the individual components of seven of the binaries formed by the combination of these five compounds. Since both procedures described quasi-ideal behavior for all the chosen solutions, the results are considered as an approximation, owing to the special nature of the studied systems. The results and characteristics of each system are discussed separately.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-01-01
2022
2022-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/72304
url https://hdl.handle.net/20.500.14352/72304
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución 3.0 España
https://creativecommons.org/licenses/by/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución 3.0 España
https://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869405028623581184
score 15,301603

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