Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization
A chiral Zn porphyrin derivative 1 and its achiral analogue 2 were studied in the solid state. Considering the rich molecular recognition of designed metalloporphyrins 1 and 2 and their tendency to crystallize, they were recrystallized from two solvent mixtures (CHCl/CHOH and CHCl/hexane). As a resu...
| Autores: | , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:206939 |
| Acceso en línea: | https://ddd.uab.cat/record/206939 https://dx.doi.org/urn:doi:10.1002/chem.201802031 |
| Access Level: | acceso abierto |
| Palabra clave: | Chirality Crystal growth Self-assembly Porphyrinoids Zinc |
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Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin CrystallizationQian, Wenjie|||0000-0003-1696-8094González Campo, Arántzazu|||0000-0002-1209-8119Pérez Rodríguez, AnaRodríguez-Hermida, Sabina|||0000-0001-7671-9925Imaz, Inhar|||0000-0002-0278-1141Wurst, Klaus|||0000-0002-8774-9051Maspoch Comamala, Daniel|||0000-0003-1325-9161Ruiz, Eliseo|||0000-0001-9097-8499Ocal García, Carmen|||0000-0001-8790-8844Barrena, Esther|||0000-0001-9163-2959Amabilino, David B.|||0000-0003-1674-8462Aliaga-Alcalde, Núria|||0000-0003-1080-3862ChiralityCrystal growthSelf-assemblyPorphyrinoidsZincA chiral Zn porphyrin derivative 1 and its achiral analogue 2 were studied in the solid state. Considering the rich molecular recognition of designed metalloporphyrins 1 and 2 and their tendency to crystallize, they were recrystallized from two solvent mixtures (CHCl/CHOH and CHCl/hexane). As a result, four different crystalline arrangements (1 a,b and 2 a,b, from 0D to 2D) were obtained. Solid-state studies were performed on all the species to analyze the role played by chirality, solvent mixtures, and surfaces (mica and HOPG) in the supramolecular arrangements. By means of combinations of solvents and substrates a variety of microsized species was obtained, from vesicles to flower-shaped arrays, including geometrical microcrystals. Overall, the results emphasize the environmental susceptibility of metalloporphyrins and how this feature must be taken into account in their design. 22018-01-0120182018-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/206939https://dx.doi.org/urn:doi:10.1002/chem.201802031reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2013-47869-C4-1-PMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-65354-C2-1-RAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 MAT2016-77852-C2-1-RMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2015-64579-C3-1-PMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-68994-REDCMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2015-0496Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2069392026-06-06T12:50:31Z |
| dc.title.none.fl_str_mv |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| title |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| spellingShingle |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization Qian, Wenjie|||0000-0003-1696-8094 Chirality Crystal growth Self-assembly Porphyrinoids Zinc |
| title_short |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| title_full |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| title_fullStr |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| title_full_unstemmed |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| title_sort |
Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization |
| dc.creator.none.fl_str_mv |
Qian, Wenjie|||0000-0003-1696-8094 González Campo, Arántzazu|||0000-0002-1209-8119 Pérez Rodríguez, Ana Rodríguez-Hermida, Sabina|||0000-0001-7671-9925 Imaz, Inhar|||0000-0002-0278-1141 Wurst, Klaus|||0000-0002-8774-9051 Maspoch Comamala, Daniel|||0000-0003-1325-9161 Ruiz, Eliseo|||0000-0001-9097-8499 Ocal García, Carmen|||0000-0001-8790-8844 Barrena, Esther|||0000-0001-9163-2959 Amabilino, David B.|||0000-0003-1674-8462 Aliaga-Alcalde, Núria|||0000-0003-1080-3862 |
| author |
Qian, Wenjie|||0000-0003-1696-8094 |
| author_facet |
Qian, Wenjie|||0000-0003-1696-8094 González Campo, Arántzazu|||0000-0002-1209-8119 Pérez Rodríguez, Ana Rodríguez-Hermida, Sabina|||0000-0001-7671-9925 Imaz, Inhar|||0000-0002-0278-1141 Wurst, Klaus|||0000-0002-8774-9051 Maspoch Comamala, Daniel|||0000-0003-1325-9161 Ruiz, Eliseo|||0000-0001-9097-8499 Ocal García, Carmen|||0000-0001-8790-8844 Barrena, Esther|||0000-0001-9163-2959 Amabilino, David B.|||0000-0003-1674-8462 Aliaga-Alcalde, Núria|||0000-0003-1080-3862 |
| author_role |
author |
| author2 |
González Campo, Arántzazu|||0000-0002-1209-8119 Pérez Rodríguez, Ana Rodríguez-Hermida, Sabina|||0000-0001-7671-9925 Imaz, Inhar|||0000-0002-0278-1141 Wurst, Klaus|||0000-0002-8774-9051 Maspoch Comamala, Daniel|||0000-0003-1325-9161 Ruiz, Eliseo|||0000-0001-9097-8499 Ocal García, Carmen|||0000-0001-8790-8844 Barrena, Esther|||0000-0001-9163-2959 Amabilino, David B.|||0000-0003-1674-8462 Aliaga-Alcalde, Núria|||0000-0003-1080-3862 |
| author2_role |
author author author author author author author author author author author |
| dc.subject.none.fl_str_mv |
Chirality Crystal growth Self-assembly Porphyrinoids Zinc |
| topic |
Chirality Crystal growth Self-assembly Porphyrinoids Zinc |
| description |
A chiral Zn porphyrin derivative 1 and its achiral analogue 2 were studied in the solid state. Considering the rich molecular recognition of designed metalloporphyrins 1 and 2 and their tendency to crystallize, they were recrystallized from two solvent mixtures (CHCl/CHOH and CHCl/hexane). As a result, four different crystalline arrangements (1 a,b and 2 a,b, from 0D to 2D) were obtained. Solid-state studies were performed on all the species to analyze the role played by chirality, solvent mixtures, and surfaces (mica and HOPG) in the supramolecular arrangements. By means of combinations of solvents and substrates a variety of microsized species was obtained, from vesicles to flower-shaped arrays, including geometrical microcrystals. Overall, the results emphasize the environmental susceptibility of metalloporphyrins and how this feature must be taken into account in their design. |
| publishDate |
2018 |
| dc.date.none.fl_str_mv |
2 2018-01-01 2018 2018-01-01 |
| dc.type.none.fl_str_mv |
Article http://purl.org/coar/resource_type/c_6501 AM http://purl.org/coar/version/c_ab4af688f83e57aa |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://ddd.uab.cat/record/206939 https://dx.doi.org/urn:doi:10.1002/chem.201802031 |
| url |
https://ddd.uab.cat/record/206939 https://dx.doi.org/urn:doi:10.1002/chem.201802031 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.relation.none.fl_str_mv |
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2013-47869-C4-1-P Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-65354-C2-1-R Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 MAT2016-77852-C2-1-R Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2015-64579-C3-1-P Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-68994-REDC Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2015-0496 Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295 |
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open access http://purl.org/coar/access_right/c_abf2 https://rightsstatements.org/vocab/InC/1.0/ |
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info:eu-repo/semantics/openAccess |
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open access http://purl.org/coar/access_right/c_abf2 https://rightsstatements.org/vocab/InC/1.0/ |
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openAccess |
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application/pdf |
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reponame:Dipòsit Digital de Documents de la UAB instname:Universitat Autònoma de Barcelona |
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