Exploring the potential of conventional and flash pyrolysis methods for the valorisation of grape seed and chestnut shell biomass from agri-food industry waste

Residual biomass is a valuable and growing by-product, but often underutilized. This research aims to investigate the possible strategies for the energetic valorisation of agri-food industry wastes: grape seed and chestnut shell. Pyrolysis thermal process was the selected for this work. Applied to b...

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Detalles Bibliográficos
Autores: Pardo, R., Taboada Ruiz, Luis, Fuente Alonso, Enrique, Ruiz Bobes, Begoña, Díaz Somoano, Mercedes, Calvo, L. F., Paniagua Bermejo, Sergio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/344194
Acceso en línea:http://hdl.handle.net/10261/344194
https://api.elsevier.com/content/abstract/scopus_id/85171650339
Access Level:acceso abierto
Palabra clave:Thermal pyrolysis processes
Bio-char
Bio-fuels
Food industrial wastes
Renewable energy
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Descripción
Sumario:Residual biomass is a valuable and growing by-product, but often underutilized. This research aims to investigate the possible strategies for the energetic valorisation of agri-food industry wastes: grape seed and chestnut shell. Pyrolysis thermal process was the selected for this work. Applied to biomass, pyrolysis is a promising method for the simultaneous production of biochar, bio-oil, and gas. Two different pyrolysis processes were conducted: conventional pyrolysis at 750 °C and flash pyrolysis at 750 °C and 850 °C. Flash pyrolysis yielded superior product properties compared to conventional pyrolysis. The gas obtained through flash pyrolysis presented a four-fold higher high heating value due to increased CH4 and H2 content. Bio-oil contains over 90% of polycyclic aromatic hydrocarbons, and calorific value reached up to 32 MJ kg−1 for grape seed, which is 7% more than bioethanol HHV. Biochar can be used both as fuel or as activated carbon precursor due to its high carbon content (91%). Calorific value of chestnut shell biochar (32.7 MJ kg−1), comparable to mineral coals, increased by 72% with respect to the value of this untreated raw material. This work approved the potential of flash pyrolysis as a method to process biomass wastes in a renewable energy scenario.