Enhancement of UV absorption behavior in ZnO-TiO2 composites

[EN] The ultraviolet-visible, UV-vis, absorption edge behaviour of semiconductor oxides as TiO and ZnO promotes their use as inorganic UV filters for sunscreens. In cosmetics, the use of nanoparticles is favoured because of their higher yield and lower whiteness. However, the particle size effect in...

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Detalles Bibliográficos
Autores: Jiménez Reinosa, Julián, Leret, Pilar, Álvarez-Docio, Carmen M., Campo, Ángel Adolfo del, Fernández Lozano, José Francisco
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/200033
Acceso en línea:http://hdl.handle.net/10261/200033
Access Level:acceso abierto
Palabra clave:TiO2
ZnO
Composite
Microparticles
Nanoparticles
UV-absorption
Micropartículas
Nanopartículas
Absorción UV
Descripción
Sumario:[EN] The ultraviolet-visible, UV-vis, absorption edge behaviour of semiconductor oxides as TiO and ZnO promotes their use as inorganic UV filters for sunscreens. In cosmetics, the use of nanoparticles is favoured because of their higher yield and lower whiteness. However, the particle size effect in the UV absorption is unclear. For this reason, the performances of nano and microsized TiO and ZnO are evaluated in both the UV-vis spectroscopy and the Sun Protection Factor, SPF, value. In order to cover the UV range completely by using inorganic filters a new composite is attempted by dry nanodispersion methodology in which TiO nanoparticles are dispersed onto ZnO microparticles. The new composite shows superior UV absorbing properties and ca. 60% SPF value due to a synergism between components that resulted in extended UV coverage and reduction of the total amount of nanoparticles required in the sunscreens. In addition, nanoparticles are effectively anchored onto microparticles avoiding the presence of free nanoparticles.