Integrating gas diffusion electrode technology in a 3D-printed cell for an efficient electrochemical production of hydrogen peroxide
This work reports the performance of a 3D printed electrochemical reactor for the production of hydrogen peroxide using carbon-based electrodes. To that purpose, the gas diffusion electrode (GDE) technology was integrated in a double chamber 3D-printed cell with a Nafion membrane as a separator. To...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Universidad de Castilla-La Mancha |
| Repositorio: | RUIdeRA. Repositorio Institucional de la UCLM |
| OAI Identifier: | oai:ruidera.uclm.es:10578/43349 |
| Acceso en línea: | https://doi.org/10.1016/j.jece.2025.116894 https://hdl.handle.net/10578/43349 |
| Access Level: | acceso abierto |
| Palabra clave: | 3-D printed cell Faradaic efficiency Gas diffusion electrode Hydrogen peroxide Platinum |
| Sumario: | This work reports the performance of a 3D printed electrochemical reactor for the production of hydrogen peroxide using carbon-based electrodes. To that purpose, the gas diffusion electrode (GDE) technology was integrated in a double chamber 3D-printed cell with a Nafion membrane as a separator. To evaluate the functionality of the system, a hydraulic characterization was carried out by varying the electrolyte and oxygen flow rates through the GDE. In general terms, the electrochemical activity was shown to be highly dependent on the oxygen flow, obtaining better results at low rates (0.1 NL·min-1). The influence of adding ultra-low Pt loadings (0.0125–0.05 mgPt·cm-2) was evaluated and compared with a Pt-free GDE. The H2O2 performance and the faradaic efficiency decreased while increasing the Pt loading for all the current densities tested due to cathodic side reactions. On the other hand, the Pt-free GDE exhibited promising results, achieving a production between 15 and 330 mg·h-1 with a maximum of current efficiency of 93.5 %. These values correspond to the highest performance for H2O2 production systems reported in the current literature. |
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