Magnesium phosphate cement formulated with low grade magnesium oxide with controlled porosity and low thermal conductivity as a function of admixture

Magnesium phosphate cement (MPC) formulated with low-grade magnesium oxide (LG-MgO) can be better considered as sustainable MPC (sust-MPC). Among other properties, sust-MPC could be used as building material for constructive elements because of its acoustic and thermal insulation properties. Porosit...

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Detalles Bibliográficos
Autores: Niubó Eslava, Maria, Formosa Mitjans, Joan, Maldonado Alameda, Alex, Valle Zermeño, Ricardo del, Chimenos Ribera, Josep Ma.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/140468
Acceso en línea:https://hdl.handle.net/2445/140468
Access Level:acceso abierto
Palabra clave:Ciment
Materials de construcció
Conducció de la calor
Propietats tèrmiques
Cement
Building materials
Conduction of heat
Thermal properties
Descripción
Sumario:Magnesium phosphate cement (MPC) formulated with low-grade magnesium oxide (LG-MgO) can be better considered as sustainable MPC (sust-MPC). Among other properties, sust-MPC could be used as building material for constructive elements because of its acoustic and thermal insulation properties. Porosity and thermal conductivity are two important parameters that have a significant influence on thermal insulation properties. In this regard, this work aimed to obtain a highly porous sust-MPC with enhanced properties for thermal insulation. To this end the percentage of porosity as a function of both the amount of set-retarding admixture and the kneading water needed was assessed using a statistical design of experiments (DoE) approach. Additionally, thermal conductivity was also evaluated with respect these two factors. Last but not least, an optimized dosage was sought in order to maximize the percentage of porosity while achieving the lowest thermal conductivity. According to the results obtained, the statistical method successfully predicted the effects of variables on the final properties. Hence, a model that explains the overall behaviour of the system was successfully attained. The obtained model predicts the porosity and the thermal conductivity of sust-MPC by means of the mixture dosage. Consequently, the present work demonstrates that it is possible to control the porosity in order to diminish thermal conductivity. Keywords Insulation; building material; design of experiments; MPC; porosity; thermal conductivity