High-Efficiency Light-Emitting Diodes Based on Formamidinium Lead Bromide Nanocrystals and solution processed transport layers

Perovskite nanocrystal light-emitting diodes (LEDs) employing architecture comprising a ZnO nanoparticles electron-transport layer and a conjugated polymer hole-transport layer have been fabricated. The obtained LEDs demonstrate a maximum external-quantum-efficiency of 6.04%, luminance of 12998 Cd/m...

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Detalles Bibliográficos
Autores: Stasio, Francesco Di, Ramiro, Íñigo, Bi, Yu, Christodoulou, Sotirios, Stavrinadis, Alexandros, Konstantatos, Gerasimos
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/121078
Acceso en línea:https://hdl.handle.net/2117/121078
Access Level:acceso abierto
Palabra clave:Nanocrystals
nanocrystals
Òptica
Àrees temàtiques de la UPC::Física
Descripción
Sumario:Perovskite nanocrystal light-emitting diodes (LEDs) employing architecture comprising a ZnO nanoparticles electron-transport layer and a conjugated polymer hole-transport layer have been fabricated. The obtained LEDs demonstrate a maximum external-quantum-efficiency of 6.04%, luminance of 12998 Cd/m2 and stable electroluminescence at 519 nm. Importantly, such high efficiency and bright-ness have been achieved by employing solution processed transport layers, formamidinium lead bromide nanocrystals (CH(NH2)2PbBr3 NCs) synthesized at room-temperature and in air without the use of a Schlenk line, and a procedure based on atomic layer deposition to insolubilize the NC film. The obtained NCs show a photoluminescence quantum yield of 90% that is retained upon film fabrication. The results show that perovskite NC LEDs can achieve high-performance without the use of transport layers deposited through evaporation in ultra-high-vacuum.