An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis
Ring-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R&...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2009 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/173196 |
| Acceso en línea: | https://hdl.handle.net/2445/173196 |
| Access Level: | acceso abierto |
| Palabra clave: | Lactames Alcaloides Compostos bioactius Química orgànica Lactams Alkaloids Bioactive compounds Organic chemistry |
| Sumario: | Ring-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R') also undergoes oxidation to the corresponding cyclohexenone C. |
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