MasterChem: Cooking 2D-polymers

2D-polymers are still dominated by graphene and closely related materials such as boron nitride, transition metal sulphides and oxides. However, the rational combination of molecules with suitable design is already showing the high potential of chemistry in this new research field. The aim of this f...

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Detalles Bibliográficos
Autores: Rodríguez-San-Miguel, D., Amo Ochoa, María Pilar, Zamora Abanades, Félix Juan
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/689972
Acceso en línea:http://hdl.handle.net/10486/689972
https://dx.doi.org/10.1039/c5cc10283a
Access Level:acceso abierto
Palabra clave:Organic polymers
Microporosity
Frameworks COFs
Metal organic framework
Graphene
Polymer transition element
Two dimensional polymer
Química
Descripción
Sumario:2D-polymers are still dominated by graphene and closely related materials such as boron nitride, transition metal sulphides and oxides. However, the rational combination of molecules with suitable design is already showing the high potential of chemistry in this new research field. The aim of this feature article is to illustrate, and provide some perspectives, the current state-of-the-art in the field of synthetic 2D-polymers showing different alternatives to prepare this novel type of polymers based on the rational use of chemistry. This review comprises a brief revision of the essential concepts, the strategies of preparation following the two general approaches, bottom-up and top-down, and a revision of the promising seminal properties showed by some of these nanomaterials.