Operational feasibility of biomass combustion with in situ CO2 capture by CaO during 360 h in a 300 kWth calcium looping facility

Simultaneous biomass combustion and CO2 capture using CaO, namely in situ calcium looping, has been proposed as a potential energy generation option with negative CO2 emissions. Previous pilot plant trials have already proven the technical feasibility of this process concept in pilot plants of up to...

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Detalles Bibliográficos
Autores: Diego de Paz, María Elena, Alonso Carreño, Mónica
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/221153
Acceso en línea:http://hdl.handle.net/10261/221153
Access Level:acceso abierto
Palabra clave:BECCS
Bio-CCS
Calcium looping
Biomass combustion
Negative emissions
CO2 capture
Descripción
Sumario:Simultaneous biomass combustion and CO2 capture using CaO, namely in situ calcium looping, has been proposed as a potential energy generation option with negative CO2 emissions. Previous pilot plant trials have already proven the technical feasibility of this process concept in pilot plants of up to 300 kWth. However, this study goes a step further and analyses the operational feasibility of these systems. For this purpose, a 360 h in situ calcium looping experiment was conducted in La Robla 300 kWth facility in continuous mode, which is the longest calcium looping test so far conducted at pilot plant scale, to the best of our knowledge. Operational stability was achieved and maintained throughout the entire experiment. Control of the facility was easily kept by performing slight modifications to the biomass and air feeding rates in order to ensure adequate temperatures and active bed inventories within the reactors, as well as sufficient solid circulation rates. As a result, high normalized CO2 capture efficiencies of over 80% were achieved during most of the test. The successful results obtained not only confirm the technical viability but also prove the operational feasibility of the in situ CO2 capture concept using CaO at high temperature at the 300 kWth plant scale, which is crucial for the future development of this type of CO2 capture technology.