Protective effect of hydroxytyrosol and rosemary extract in a comparative study of the oxidative stability of Echium oil

The oxidative stability of Echium oil has been studied by two accelerated oxidation methodologies namely Rancimat and differential scanning calorimetry at selected temperatures in the range 50–110 °C. Kinetic analyses have provided Arrhenius parameters, oxidative stability indexes (OSI), temperature...

Descripción completa

Detalles Bibliográficos
Autores: Bañares Echevarria, Celia, Reglero Rada, Guillermo J., Martín García, Diana, Torres Olivares, Carlos Fernando
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/717810
Acceso en línea:http://hdl.handle.net/10486/717810
https://dx.doi.org/10.1016/j.foodchem.2019.03.141
Access Level:acceso abierto
Palabra clave:Carnosic acid
differential scanning calorimetry
echium oil
hydroxytyrosol
oxidative stability
rancimat test
rosemary extract
stearidonic acid
Ciencia y Tecnología de Alimentos
Descripción
Sumario:The oxidative stability of Echium oil has been studied by two accelerated oxidation methodologies namely Rancimat and differential scanning calorimetry at selected temperatures in the range 50–110 °C. Kinetic analyses have provided Arrhenius parameters, oxidative stability indexes (OSI), temperature coefficients (t coef ), Q 10 and OSI at 20 °C (OSI 20 ) for both methodologies focussing on secondary and tertiary oxidation products. Peroxide, p-anisidine and polar compounds values have been measured to characterize from primary to tertiary oxidation products. In general, susceptibility of this oil to oxidation has been found to be larger than for other vegetable oils, according to the OSI 20 values estimated by Rancimat and differential scanning calorimetry. However, the values of t coeff and Q 10 are found to be similar to those described for vegetable oils. In addition, a study of the influence of two antioxidants, namely hydroxytyrosol and rosemary extract on the oxidative stability of Echium oil has been carried out using both methodologies. Protective effects over oxidation by up to a threefold increase of OSI 20 values have been found for both antioxidants at the highest dose utilized