Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water

Cortés Martínez, Alba; Fernández-Seriñán, Pilar; Baeckmann, Cornelia von; Caules, Caterina; Hernández-López, Laura; Gutiérrez, María Susana; Yang, Yunhui; Sánchez-Naya, Roberto; Suárez, José Antonio; Juanhuix, Judith; Imaz, Inhar; Carné-Sánchez, Arnau; Maspoch, Daniel

Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water

Synthesis of mesoporous metal-organic cages or polyhedra (MOCs or MOPs) that retain their porous functionality in the solid-state remains challenging, given their tendency to collapse upon desolvation. Herein, we report the use of the isoreticular expansion approach to synthesize two permanently por...

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Autores:	Cortés Martínez, Alba, Fernández-Seriñán, Pilar, Baeckmann, Cornelia von, Caules, Caterina, Hernández-López, Laura, Gutiérrez, María Susana, Yang, Yunhui, Sánchez-Naya, Roberto, Suárez, José Antonio, Juanhuix, Judith, Imaz, Inhar, Carné-Sánchez, Arnau, Maspoch, Daniel
Tipo de recurso:	artículo
Estado:	Versión publicada
Fecha de publicación:	2025
País:	España
Institución:	Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:	DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:	oai:digital.csic.es:10261/399352
Acceso en línea:	http://hdl.handle.net/10261/399352 https://api.elsevier.com/content/abstract/scopus_id/105006923650
Access Level:	acceso abierto
Palabra clave:	Cages Mesoporous Metal‐organic polygons Metal‐organic polyhedra Water adsorption

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network_acronym_str	ES
network_name_str	España
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dc.title.none.fl_str_mv	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
title	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
spellingShingle	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water Cortés Martínez, Alba Cages Mesoporous Metal‐organic polygons Metal‐organic polyhedra Water adsorption
title_short	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
title_full	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
title_fullStr	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
title_full_unstemmed	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
title_sort	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water
dc.creator.none.fl_str_mv	Cortés Martínez, Alba Fernández-Seriñán, Pilar Baeckmann, Cornelia von Caules, Caterina Hernández-López, Laura Gutiérrez, María Susana Yang, Yunhui Sánchez-Naya, Roberto Suárez, José Antonio Juanhuix, Judith Imaz, Inhar Carné-Sánchez, Arnau Maspoch, Daniel
author	Cortés Martínez, Alba
author_facet	Cortés Martínez, Alba Fernández-Seriñán, Pilar Baeckmann, Cornelia von Caules, Caterina Hernández-López, Laura Gutiérrez, María Susana Yang, Yunhui Sánchez-Naya, Roberto Suárez, José Antonio Juanhuix, Judith Imaz, Inhar Carné-Sánchez, Arnau Maspoch, Daniel
author_role	author
author2	Fernández-Seriñán, Pilar Baeckmann, Cornelia von Caules, Caterina Hernández-López, Laura Gutiérrez, María Susana Yang, Yunhui Sánchez-Naya, Roberto Suárez, José Antonio Juanhuix, Judith Imaz, Inhar Carné-Sánchez, Arnau Maspoch, Daniel
author2_role	author author author author author author author author author author author author
dc.contributor.none.fl_str_mv	European Commission Ministerio de Ciencia e Innovación (España) Agencia Estatal de Investigación (España) Generalitat de Catalunya Consejo Superior de Investigaciones Científicas (España) Austrian Science Fund Erwin Schrödinger Center for Quantum Science & Technology China Scholarship Council Consejo Nacional de Ciencia y Tecnología (Paraguay) Maspoch, Daniel [0000-0003-1325-9161] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv	Cages Mesoporous Metal‐organic polygons Metal‐organic polyhedra Water adsorption
topic	Cages Mesoporous Metal‐organic polygons Metal‐organic polyhedra Water adsorption
description	Synthesis of mesoporous metal-organic cages or polyhedra (MOCs or MOPs) that retain their porous functionality in the solid-state remains challenging, given their tendency to collapse upon desolvation. Herein, we report the use of the isoreticular expansion approach to synthesize two permanently porous Rh(II)-based octahedral MOPs within the mesoporous regime. Our mesoporous MOPs, featuring internal cavities of up to 12.5 nm3, withstand the activation process, enabling their use as solid-state adsorbents for gases and water. In particular, the largest mesoporous MOP, named BCN-17, captures up to 0.47 gwater·gMOP -1 and exhibits an S-shaped water-sorption isotherm with a hysteresis loop, characteristic of mesoporous materials.
publishDate	2025
dc.date.none.fl_str_mv	2025 2025 2025
dc.type.none.fl_str_mv	info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/10261/399352 https://api.elsevier.com/content/abstract/scopus_id/105006923650
url	http://hdl.handle.net/10261/399352 https://api.elsevier.com/content/abstract/scopus_id/105006923650
dc.language.none.fl_str_mv	Inglés
language_invalid_str_mv	Inglés
dc.relation.none.fl_str_mv	#PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/H2020/101019003 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-124804NB-I00 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2021-001214-S info:eu-repo/grantAgreement/AEI//RYC2020-029749-I The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1002/anie.202505682 Cortés Martínez, Alba; Fernández-Seriñán, Pilar; Baeckmann, Cornelia von; Caules, Caterina; Hernández-López, Laura; Gutiérrez, María Susana; Yang, Yunhui; Sánchez-Naya, Roberto; Suárez, José Antonio; Juanhuix, Judith; Imaz, Inhar; Carné-Sánchez, Arnau; Maspoch, Daniel; 2025; Electronic Supporting Information: Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water; Wiley-VCH; Gesellschaft Deutscher Chemiker; https://doi.org/10.1002/anie.202505682 https://doi.org/10.1002/anie.202505682 Sí
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess
eu_rights_str_mv	openAccess
dc.format.none.fl_str_mv	application/pdf
dc.publisher.none.fl_str_mv	Wiley-VCH Gesellschaft Deutscher Chemiker
publisher.none.fl_str_mv	Wiley-VCH Gesellschaft Deutscher Chemiker
dc.source.none.fl_str_mv	reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str	Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str	DIGITAL.CSIC. Repositorio Institucional del CSIC
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spelling	Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and WaterCortés Martínez, AlbaFernández-Seriñán, PilarBaeckmann, Cornelia vonCaules, CaterinaHernández-López, LauraGutiérrez, María SusanaYang, YunhuiSánchez-Naya, RobertoSuárez, José AntonioJuanhuix, JudithImaz, InharCarné-Sánchez, ArnauMaspoch, DanielCagesMesoporousMetal‐organic polygonsMetal‐organic polyhedraWater adsorptionSynthesis of mesoporous metal-organic cages or polyhedra (MOCs or MOPs) that retain their porous functionality in the solid-state remains challenging, given their tendency to collapse upon desolvation. Herein, we report the use of the isoreticular expansion approach to synthesize two permanently porous Rh(II)-based octahedral MOPs within the mesoporous regime. Our mesoporous MOPs, featuring internal cavities of up to 12.5 nm3, withstand the activation process, enabling their use as solid-state adsorbents for gases and water. In particular, the largest mesoporous MOP, named BCN-17, captures up to 0.47 gwater·gMOP -1 and exhibits an S-shaped water-sorption isotherm with a hysteresis loop, characteristic of mesoporous materials.This work has received funding from the European Union's Horizon 2020 research and innovation program under grant agreement no. 101019003, grant refs. PID2021-124804NB-I00 funded by MCIN/AEI/10.13039/501100011033/ and by “ERDF A way of making Europe”, and the Catalan AGAUR (project 2021 SGR 00458). It was also funded by the CERCA Programme/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa Centres of Excellence program, Grant CEX2021-001214-S, funded by MCIN/AEI/10.13039.501100011033. A.C.S. is indebted to the Ramón y Cajal Program (RYC2020-029749-I Fellowship). C.v.B. thanks the Austrian Science Fund (FWF), Erwin Schrödinger fellowship for supporting the project J 4637. Y.Y. acknowledges the China Scholarship Council for scholarship support. M.S.G acknowledges the CONACyT for scholarship support.With funding from the Spanish government through the "Severo Ochoa Centre of Excelence" accreditation (CEX2021-001214-S)Peer reviewedWiley-VCHGesellschaft Deutscher ChemikerEuropean CommissionMinisterio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)Generalitat de CatalunyaConsejo Superior de Investigaciones Científicas (España)Austrian Science FundErwin Schrödinger Center for Quantum Science & TechnologyChina Scholarship CouncilConsejo Nacional de Ciencia y Tecnología (Paraguay)Maspoch, Daniel [0000-0003-1325-9161]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/399352https://api.elsevier.com/content/abstract/scopus_id/105006923650reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/101019003info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-124804NB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2021-001214-Sinfo:eu-repo/grantAgreement/AEI//RYC2020-029749-IThe underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1002/anie.202505682Cortés Martínez, Alba; Fernández-Seriñán, Pilar; Baeckmann, Cornelia von; Caules, Caterina; Hernández-López, Laura; Gutiérrez, María Susana; Yang, Yunhui; Sánchez-Naya, Roberto; Suárez, José Antonio; Juanhuix, Judith; Imaz, Inhar; Carné-Sánchez, Arnau; Maspoch, Daniel; 2025; Electronic Supporting Information: Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water; Wiley-VCH; Gesellschaft Deutscher Chemiker; https://doi.org/10.1002/anie.202505682https://doi.org/10.1002/anie.202505682Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3993522026-05-22T06:33:51Z
score	15,811543

Isoreticular Synthesis of Mesoporous Metal-Organic Polyhedra with Permanent Porosity to Gas and Water

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