Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework

The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses...

Descripción completa

Detalles Bibliográficos
Autores: Sastre Navarro, German Ignacio|||0000-0003-0496-6331, van den Bergh, Johan, Kapteijn, Freek, Denysenko, Dmytro, Volkmer, Dirk
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/70157
Acceso en línea:https://riunet.upv.es/handle/10251/70157
Access Level:acceso abierto
Palabra clave:Metal-organic frameworks
Adsorption
Descripción
Sumario:The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N-2.

Similares en LA Referencia