Electrocatalytic self-assembled multilayer structures based on thiolated Fc-DAB dendrimers: Determination of heavy metal ions by enzymatic inhibition

The development of sensitive and rapid inhibition-based biosensors for monitoring trace levels of heavy metals such as lead and copper ions in environmental samples is of high interest. In this work, we describe the fabrication of HRP sensitive peroxide biosensors based on ferrocenyl thiolated DAB d...

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Detalles Bibliográficos
Autores: Ospina, Evelyn, Alonso Garrido, Beatriz, Casado Santana, Carmen, García Armada, M. Pilar
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/708660
Acceso en línea:http://hdl.handle.net/10486/708660
https://dx.doi.org/10.1016/j.cattod.2023.114293
Access Level:acceso abierto
Palabra clave:Dendrimers
Gold Nanoparticles
Iron Compounds
Organometallics
Metal Nanoparticles
Química
Descripción
Sumario:The development of sensitive and rapid inhibition-based biosensors for monitoring trace levels of heavy metals such as lead and copper ions in environmental samples is of high interest. In this work, we describe the fabrication of HRP sensitive peroxide biosensors based on ferrocenyl thiolated DAB dendrimers as bonding-layer between electrodeposited and colloidal gold nanoparticles and compare their electrocatalytic properties with those of thiolated DAB homologues. The complete electrochemical, kinetic and analytical characterization of these new heavy metals’ inhibition-biosensors are investigated