Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles

This work addresses the preparation of new polymer dielectrics working under the dipolar glass polymer (DGP) concept. Herein, we report the synthesis and characterization of four hetero-functionalized polyitaconates bearing sulfones as high dipole moment entities and norbornane or adamantane structu...

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Autores: Bonardd, Sebastián, Maiz, Jon, Alegría, Ángel, Pomposo, José A., Verde-Sesto, Ester, Kortaberria, Galder, Díaz Díaz, David
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/356077
Acesso em linha:http://hdl.handle.net/10261/356077
Access Level:acceso abierto
Palavra-chave:Polymer dielectrics
Dipolar glass polymers
Polyitaconates
Energy storage
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dc.title.none.fl_str_mv Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
title Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
spellingShingle Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
Bonardd, Sebastián
Polymer dielectrics
Dipolar glass polymers
Polyitaconates
Energy storage
title_short Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
title_full Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
title_fullStr Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
title_full_unstemmed Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
title_sort Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cycles
dc.creator.none.fl_str_mv Bonardd, Sebastián
Maiz, Jon
Alegría, Ángel
Pomposo, José A.
Verde-Sesto, Ester
Kortaberria, Galder
Díaz Díaz, David
author Bonardd, Sebastián
author_facet Bonardd, Sebastián
Maiz, Jon
Alegría, Ángel
Pomposo, José A.
Verde-Sesto, Ester
Kortaberria, Galder
Díaz Díaz, David
author_role author
author2 Maiz, Jon
Alegría, Ángel
Pomposo, José A.
Verde-Sesto, Ester
Kortaberria, Galder
Díaz Díaz, David
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
European Commission
Ministerio de Ciencia e Innovación (España)
Agencia Estatal de Investigación (España)
Eusko Jaurlaritza
Diputación Foral de Gipuzkoa
Cabildo de Tenerife
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Polymer dielectrics
Dipolar glass polymers
Polyitaconates
Energy storage
topic Polymer dielectrics
Dipolar glass polymers
Polyitaconates
Energy storage
description This work addresses the preparation of new polymer dielectrics working under the dipolar glass polymer (DGP) concept. Herein, we report the synthesis and characterization of four hetero-functionalized polyitaconates bearing sulfones as high dipole moment entities and norbornane or adamantane structures responsible for increasing the glass transition temperature (Tg) and thus the range of temperatures where they can work without degrading or showing high energy dissipation. As a result, all obtained polymers exhibited dielectric constants (εr’) between 5.1 and 6.2 while presenting low loss factors (Tan(δ) < 0.01), reaching the status of high-dielectric polymers with a low dissipative behavior. In addition, it was demonstrated that including bulky structures into their polymer backbone allows for an increase of up to 80 °C in their working temperature ranges, expanding the temperature range where they behave as DGPs in an outstanding manner. A complete structural, thermal and dielectric characterization was carried out in terms of infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), thermogravimetry (TGA), differential scanning calorimetry (DSC) and broad dielectric spectroscopy (BDS). Overall, these materials seem to fulfill the basic requirements to be considered good candidates for dielectric applications such as energy storage, confirming the versatility of polyitaconate-based materials.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
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info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/356077
url http://hdl.handle.net/10261/356077
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123438NB-I00
info:eu-repo/grantAgreement/AEI//TED2021-130107A-I00
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105391GB-C21
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.reactfunctpolym.2024.105842
https://doi.org/10.1016/j.reactfunctpolym.2024.105842
Sí
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dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
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spelling Hetero-functionalization of polyitaconates for developing improved polymer dielectrics: Merging sulfones with bulky/rigid cyclesBonardd, SebastiánMaiz, JonAlegría, ÁngelPomposo, José A.Verde-Sesto, EsterKortaberria, GalderDíaz Díaz, DavidPolymer dielectricsDipolar glass polymersPolyitaconatesEnergy storageThis work addresses the preparation of new polymer dielectrics working under the dipolar glass polymer (DGP) concept. Herein, we report the synthesis and characterization of four hetero-functionalized polyitaconates bearing sulfones as high dipole moment entities and norbornane or adamantane structures responsible for increasing the glass transition temperature (Tg) and thus the range of temperatures where they can work without degrading or showing high energy dissipation. As a result, all obtained polymers exhibited dielectric constants (εr’) between 5.1 and 6.2 while presenting low loss factors (Tan(δ) < 0.01), reaching the status of high-dielectric polymers with a low dissipative behavior. In addition, it was demonstrated that including bulky structures into their polymer backbone allows for an increase of up to 80 °C in their working temperature ranges, expanding the temperature range where they behave as DGPs in an outstanding manner. A complete structural, thermal and dielectric characterization was carried out in terms of infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), thermogravimetry (TGA), differential scanning calorimetry (DSC) and broad dielectric spectroscopy (BDS). Overall, these materials seem to fulfill the basic requirements to be considered good candidates for dielectric applications such as energy storage, confirming the versatility of polyitaconate-based materials.The Polymers & Soft Matter team acknowledges the funding provided by Grant No. PID2021-123438NB-I00 from MCIN/AEI/10.13039/501100011033, as well as the support from “ERDF A way of making Europe,” Grant No. TED2021-130107 A-I00, also funded by MCIN/AEI/10.13039/501100011033, and Unión Europea “NextGenerationEU/PRTR.” Additionally, we acknowledge the financial support from Eusko Jaurlaritza under code: IT1566-22 and Gipuzkoako Foru Aldundia, Programa de Red Guipuzcoana de Ciencia,Tecnología e Innovación, code: 2023-CIEN-000069-01. G. K. thanks to Ministerio de Ciencia, Innovacion y Universidades, grant number PID2021-126417NB-I00 and by the Gobierno Vasco/Eusko Jaurlaritza, grant number IT1690-22. D. D. D. thanks the Spanish Ministry of Science, Innovation and Universities for the grants TED2021-132847B-I00 and PID2019-105391GB-C21 funded by MCIN/AEI/10.13039/501100011033 and NANOtec, INTech, Cabildo de Tenerife and ULL for laboratory facilities.Peer reviewedElsevierMinisterio de Ciencia, Innovación y Universidades (España)European CommissionMinisterio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)Eusko JaurlaritzaDiputación Foral de GipuzkoaCabildo de TenerifeConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/356077reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123438NB-I00info:eu-repo/grantAgreement/AEI//TED2021-130107A-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126417NB-I00info:eu-repo/grantAgreement/AEI//TED2021-132847B-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105391GB-C21The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.reactfunctpolym.2024.105842https://doi.org/10.1016/j.reactfunctpolym.2024.105842Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3560772026-05-22T06:33:51Z
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