Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control

[EN] Rhodium (Rh)-supported zeolites are intensively studied as solid catalysts for the industrial hydroformylation reaction in order to replace the currently used soluble Rh catalysts. Here, we show that the counterbalancing cations of the zeolite, inherent to these aluminosilicates, significantly...

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Autores: Serrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854X, Leyva Perez, Antonio|||0000-0003-1063-5811, Singh, Amravati Shivaji, Manzorro, Ramon, Hernandez-Garrido, Juan C.
Tipo de documento: artigo
Data de publicação:2026
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:dnet:riunet______::d6dd31c975e5e0a167cd82d367fca400
Acesso em linha:https://riunet.upv.es/handle/10251/234617
Access Level:Acceso aberto
Palavra-chave:Rhodium-supported zeolites
Hydroformylation reaction
Catalytic activity
Zeolite cations
Heterogeneous catalysis
Structure-activity relationship
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spelling Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation controlSerrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854XLeyva Perez, Antonio|||0000-0003-1063-5811Singh, Amravati ShivajiManzorro, RamonHernandez-Garrido, Juan C.Rhodium-supported zeolitesHydroformylation reactionCatalytic activityZeolite cationsHeterogeneous catalysisStructure-activity relationship[EN] Rhodium (Rh)-supported zeolites are intensively studied as solid catalysts for the industrial hydroformylation reaction in order to replace the currently used soluble Rh catalysts. Here, we show that the counterbalancing cations of the zeolite, inherent to these aluminosilicates, significantly impact on the catalytic activity and selectivity of the hydroformylation reaction when sub-nanome ter Rh1+-oxide species, generated inside the zeolite after incorporation and calcination of simple Rh species, are employed as catalytic sites. A Rh-supported faujasitic structure-activity relationship is thus provided for the hydroformylation reaction, perhaps extensible to other reactions. The ligand-free Rh zeolites can now be rationally chosen for one or another alkene reactant and also to perform one-pot hydroformylation/acid catalyzed reactions, thus opening new ways to design solid catalysts for these paramount reactions.This work is part of the project PID2023-148441NB-I00 funded by MICIIN (Spain) . Thanks are also extended to the Severo Ochoa Centers of Excellence program (CEX2021-001230-S) .Cell PressInstituto Universitario Mixto de Tecnología QuímicaAgencia Estatal de InvestigaciónRepositorio Institucional de la Universitat Politècnica de València Riunet20262026-03-18journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/234617reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2023-148441NB-I00 NANORREACTORES SOLIDOS MODULABLES A ESCALA DE SUB-ANGSTROMS PARA REACCIONES ORGANICAS REGIO-IRREGULARESAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-Sopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:dnet:riunet______::d6dd31c975e5e0a167cd82d367fca4002026-06-13T07:49:27Z
dc.title.none.fl_str_mv Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
title Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
spellingShingle Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
Serrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854X
Rhodium-supported zeolites
Hydroformylation reaction
Catalytic activity
Zeolite cations
Heterogeneous catalysis
Structure-activity relationship
title_short Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
title_full Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
title_fullStr Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
title_full_unstemmed Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
title_sort Sub-nanometer Rh1+ oxide in zeolites catalyzes the hydroformylation reaction under counterbalancing cation control
dc.creator.none.fl_str_mv Serrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854X
Leyva Perez, Antonio|||0000-0003-1063-5811
Singh, Amravati Shivaji
Manzorro, Ramon
Hernandez-Garrido, Juan C.
author Serrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854X
author_facet Serrano-Maldonado, Jorge Alejandro|||0000-0003-3076-854X
Leyva Perez, Antonio|||0000-0003-1063-5811
Singh, Amravati Shivaji
Manzorro, Ramon
Hernandez-Garrido, Juan C.
author_role author
author2 Leyva Perez, Antonio|||0000-0003-1063-5811
Singh, Amravati Shivaji
Manzorro, Ramon
Hernandez-Garrido, Juan C.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
Agencia Estatal de Investigación
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Rhodium-supported zeolites
Hydroformylation reaction
Catalytic activity
Zeolite cations
Heterogeneous catalysis
Structure-activity relationship
topic Rhodium-supported zeolites
Hydroformylation reaction
Catalytic activity
Zeolite cations
Heterogeneous catalysis
Structure-activity relationship
description [EN] Rhodium (Rh)-supported zeolites are intensively studied as solid catalysts for the industrial hydroformylation reaction in order to replace the currently used soluble Rh catalysts. Here, we show that the counterbalancing cations of the zeolite, inherent to these aluminosilicates, significantly impact on the catalytic activity and selectivity of the hydroformylation reaction when sub-nanome ter Rh1+-oxide species, generated inside the zeolite after incorporation and calcination of simple Rh species, are employed as catalytic sites. A Rh-supported faujasitic structure-activity relationship is thus provided for the hydroformylation reaction, perhaps extensible to other reactions. The ligand-free Rh zeolites can now be rationally chosen for one or another alkene reactant and also to perform one-pot hydroformylation/acid catalyzed reactions, thus opening new ways to design solid catalysts for these paramount reactions.
publishDate 2026
dc.date.none.fl_str_mv 2026
2026-03-18
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/234617
url https://riunet.upv.es/handle/10251/234617
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2023-148441NB-I00 NANORREACTORES SOLIDOS MODULABLES A ESCALA DE SUB-ANGSTROMS PARA REACCIONES ORGANICAS REGIO-IRREGULARES
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-S
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Cell Press
publisher.none.fl_str_mv Cell Press
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812429

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