Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids

The use of CO2 as a C1 carbon source for synthesis is raising increasing attention both as a strategy to bring value to carbon dioxide capture technologies and a sustainable approach towards chemicals and energy. The presented results focus on the application of electrochemical methods to incorporat...

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Autores: Mena Fernández, Silvia|||0000-0002-2800-2388, Santiago Malagon, Sara|||0000-0002-1206-1455, Gallardo, Iluminada|||0000-0003-3962-4745, Guirado, Gonzalo|||0000-0003-2128-7007
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:274566
Acceso en línea:https://ddd.uab.cat/record/274566
https://dx.doi.org/urn:doi:10.1016/j.chemosphere.2019.125557
Access Level:acceso abierto
Palabra clave:Ionic Liquids
Electrochemistry
Carbon Dioxide
Naproxen
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spelling Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquidsMena Fernández, Silvia|||0000-0002-2800-2388Santiago Malagon, Sara|||0000-0002-1206-1455Gallardo, Iluminada|||0000-0003-3962-4745Guirado, Gonzalo|||0000-0003-2128-7007Ionic LiquidsElectrochemistryCarbon DioxideNaproxenThe use of CO2 as a C1 carbon source for synthesis is raising increasing attention both as a strategy to bring value to carbon dioxide capture technologies and a sustainable approach towards chemicals and energy. The presented results focus on the application of electrochemical methods to incorporate CO2 into organic compounds using ionic liquids as electrolytes, which provides a green alternative to the formation of C-C bonds. In this sense, the current manuscript shows that Naproxen (6-Methoxy-α-methyl-2-naphthaleneacetic acid) can be synthetizing in high yield (89%) and conversion rates (90%) through an electrocarboxylation process using CO2 and ionic liquids. The role of the cathode and solvent, which can potentially enhance the synthesis, is also discussed. The "green" route described in the current work would open a new sustainable strategy for the electrochemical production of pharmaceutical compounds. 22020-01-0120202020-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/274566https://dx.doi.org/urn:doi:10.1016/j.chemosphere.2019.125557reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2015-65439-RAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 CTQ2017-90659-REDTopen accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2745662026-06-06T12:50:31Z
dc.title.none.fl_str_mv Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
title Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
spellingShingle Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
Mena Fernández, Silvia|||0000-0002-2800-2388
Ionic Liquids
Electrochemistry
Carbon Dioxide
Naproxen
title_short Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
title_full Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
title_fullStr Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
title_full_unstemmed Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
title_sort Sustainable and efficient electrosynthesis of naproxen using carbon dioxide and ionic liquids
dc.creator.none.fl_str_mv Mena Fernández, Silvia|||0000-0002-2800-2388
Santiago Malagon, Sara|||0000-0002-1206-1455
Gallardo, Iluminada|||0000-0003-3962-4745
Guirado, Gonzalo|||0000-0003-2128-7007
author Mena Fernández, Silvia|||0000-0002-2800-2388
author_facet Mena Fernández, Silvia|||0000-0002-2800-2388
Santiago Malagon, Sara|||0000-0002-1206-1455
Gallardo, Iluminada|||0000-0003-3962-4745
Guirado, Gonzalo|||0000-0003-2128-7007
author_role author
author2 Santiago Malagon, Sara|||0000-0002-1206-1455
Gallardo, Iluminada|||0000-0003-3962-4745
Guirado, Gonzalo|||0000-0003-2128-7007
author2_role author
author
author
dc.subject.none.fl_str_mv Ionic Liquids
Electrochemistry
Carbon Dioxide
Naproxen
topic Ionic Liquids
Electrochemistry
Carbon Dioxide
Naproxen
description The use of CO2 as a C1 carbon source for synthesis is raising increasing attention both as a strategy to bring value to carbon dioxide capture technologies and a sustainable approach towards chemicals and energy. The presented results focus on the application of electrochemical methods to incorporate CO2 into organic compounds using ionic liquids as electrolytes, which provides a green alternative to the formation of C-C bonds. In this sense, the current manuscript shows that Naproxen (6-Methoxy-α-methyl-2-naphthaleneacetic acid) can be synthetizing in high yield (89%) and conversion rates (90%) through an electrocarboxylation process using CO2 and ionic liquids. The role of the cathode and solvent, which can potentially enhance the synthesis, is also discussed. The "green" route described in the current work would open a new sustainable strategy for the electrochemical production of pharmaceutical compounds.
publishDate 2020
dc.date.none.fl_str_mv 2
2020-01-01
2020
2020-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/274566
https://dx.doi.org/urn:doi:10.1016/j.chemosphere.2019.125557
url https://ddd.uab.cat/record/274566
https://dx.doi.org/urn:doi:10.1016/j.chemosphere.2019.125557
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 CTQ2015-65439-R
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CTQ2017-90659-REDT
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
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