Magnetic order or charge-density wave in La2NiO4 by Mössbauer spectroscopy
Measurements of Mössbauer absorption spectra of 57 Fe : La 2 Ni O 4 at 297, 77, and 4.2 K provide evidence, at the lowest temperatures, of magnetic order in a sample containing 57 Fe 3 + -ion impurities and some La 2 + n Ni 1 + n O 4 + 3 n intergrowth. Mössbauer emission spectra of 57 Co : La 2 Ni O...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1984 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/9722 |
| Acceso en línea: | https://hdl.handle.net/2445/9722 |
| Access Level: | acceso abierto |
| Palabra clave: | Espectroscòpia Mössbauer Mössbauer spectroscopy |
| Sumario: | Measurements of Mössbauer absorption spectra of 57 Fe : La 2 Ni O 4 at 297, 77, and 4.2 K provide evidence, at the lowest temperatures, of magnetic order in a sample containing 57 Fe 3 + -ion impurities and some La 2 + n Ni 1 + n O 4 + 3 n intergrowth. Mössbauer emission spectra of 57 Co : La 2 Ni O 4 at 77 and 4.2 K show magnetic order coexisting with paramagnetism in a sample containing a small concentration of 57 Co -ion impurities and some La 2 + n Ni 1 + n O 4 + 3 n intergrowth. These results are interpreted as evidence for competition between magnetic ordering and charge-density-wave formation among electrons of a narrow σ ∗ x 2 − y 2 band; intergrowths, impurities, and nonstoichiometry favor magnetic ordering. |
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