Characterization of the polymer/particle interphase in composite materials by molecular probing

11 figures, 5 tables.-- Supplementary information available.-- © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/

Detalles Bibliográficos
Autores: Maghami, Saeid, Shahrooz, Mahdi, Mehrabani-Zeinabad, Arjomand, Zornoza, Beatriz, Sadeghi, Morteza
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2020
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/221209
Acceso en línea:http://hdl.handle.net/10261/221209
Access Level:acceso abierto
Palabra clave:Mixed-matrix membrane
Permeability
Interfacial morphology
Interphase thickness
Mathematical modelling
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spelling Characterization of the polymer/particle interphase in composite materials by molecular probingMaghami, SaeidShahrooz, MahdiMehrabani-Zeinabad, ArjomandZornoza, BeatrizSadeghi, MortezaMixed-matrix membranePermeabilityInterfacial morphologyInterphase thicknessMathematical modelling11 figures, 5 tables.-- Supplementary information available.-- © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/In this study, a new method was developed for the characterization of the interface morphology in polymer/particle composites. This method, not limited to a specific polymer or particle, utilizes the gas permeability of the composites to determine the interfacial properties such as the type of polymer-particle interactions as well as the thickness and the transport properties of the interphase. Moreover, it can be employed to determine the size of the aggregates in the case of particle aggregation. The proposed method was evaluated by comparing its results with the findings of the small-angle X-ray scattering (SAXS) analysis for polyethersulfone (PES)-based composites containing pristine and fumed silica nanoparticles. Our method was also evaluated by analyzing the results of other studies obtained from the literature.B.Z. acknowledges the “Juan de la Cierva” Program (IJCI-2016-30776).Peer reviewedElsevierMinisterio de Economía, Industria y Competitividad (España)Maghami, Saeid [0000-0002-5830-2242]Shahrooz, Mahdi [0000-0002-0471-8461Mehrabani-Zeinabad, Arjomand [0000-0003-3421-1810]Zornoza, Beatriz [0000-0002-9934-1707]Sadeghi, Morteza [0000-0002-0075-1520]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202020202020info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/221209reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-30776http://dx.doi.org/10.1016/j.polymer.2020.122792Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2212092026-05-22T06:33:51Z
dc.title.none.fl_str_mv Characterization of the polymer/particle interphase in composite materials by molecular probing
title Characterization of the polymer/particle interphase in composite materials by molecular probing
spellingShingle Characterization of the polymer/particle interphase in composite materials by molecular probing
Maghami, Saeid
Mixed-matrix membrane
Permeability
Interfacial morphology
Interphase thickness
Mathematical modelling
title_short Characterization of the polymer/particle interphase in composite materials by molecular probing
title_full Characterization of the polymer/particle interphase in composite materials by molecular probing
title_fullStr Characterization of the polymer/particle interphase in composite materials by molecular probing
title_full_unstemmed Characterization of the polymer/particle interphase in composite materials by molecular probing
title_sort Characterization of the polymer/particle interphase in composite materials by molecular probing
dc.creator.none.fl_str_mv Maghami, Saeid
Shahrooz, Mahdi
Mehrabani-Zeinabad, Arjomand
Zornoza, Beatriz
Sadeghi, Morteza
author Maghami, Saeid
author_facet Maghami, Saeid
Shahrooz, Mahdi
Mehrabani-Zeinabad, Arjomand
Zornoza, Beatriz
Sadeghi, Morteza
author_role author
author2 Shahrooz, Mahdi
Mehrabani-Zeinabad, Arjomand
Zornoza, Beatriz
Sadeghi, Morteza
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía, Industria y Competitividad (España)
Maghami, Saeid [0000-0002-5830-2242]
Shahrooz, Mahdi [0000-0002-0471-8461
Mehrabani-Zeinabad, Arjomand [0000-0003-3421-1810]
Zornoza, Beatriz [0000-0002-9934-1707]
Sadeghi, Morteza [0000-0002-0075-1520]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Mixed-matrix membrane
Permeability
Interfacial morphology
Interphase thickness
Mathematical modelling
topic Mixed-matrix membrane
Permeability
Interfacial morphology
Interphase thickness
Mathematical modelling
description 11 figures, 5 tables.-- Supplementary information available.-- © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
publishDate 2020
dc.date.none.fl_str_mv 2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/221209
url http://hdl.handle.net/10261/221209
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-30776
http://dx.doi.org/10.1016/j.polymer.2020.122792
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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