Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion

El mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2016, vol. 128, núm. 22, p.6640–6644. DOI http://dx.doi.org/10.1002/ange.201601750

Detalles Bibliográficos
Autores: Conde Fernández, Ana, Sabeña Vila, Gerard, Rodríguez Serrat, Mònica, Postils Ribó, Verònica, Luis Luis, Josep Maria, Díaz Requejo, M. Mar, Costas Salgueiro, Miquel, Pérez, Pedro J.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/13145
Acceso en línea:http://hdl.handle.net/10256/13145
Access Level:acceso abierto
Palabra clave:Catalitzadors
Catalysts
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spelling Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene InsertionConde Fernández, AnaSabeña Vila, GerardRodríguez Serrat, MònicaPostils Ribó, VerònicaLuis Luis, Josep MariaDíaz Requejo, M. MarCostas Salgueiro, MiquelPérez, Pedro J.CatalitzadorsCatalystsEl mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2016, vol. 128, núm. 22, p.6640–6644. DOI http://dx.doi.org/10.1002/ange.201601750El títol de la versió postprint és "Introducing Fe and Mn as catalysts for the selective functionalization of Csp 2-H bonds of arenes by carbene insertion"The first examples of the direct functionalization of non-activated aryl sp2 C-H bonds with ethyl diazoacetate (N2CHCO2Et) catalyzed by Mn- or Fe-based complexes in a completely selective manner are reported, with no formation of the frequently observed cycloheptatriene derivatives through competing Buchner reaction. The best catalysts are FeII or MnII complexes bearing the tetradentate pytacn ligand (pytacn= 1-(2-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane). When using alkylbenzenes, the alkylic C(sp3)-H bonds of the substituents remained unmodified, thus the reaction being also selective toward functionalization of sp2 C-H bonds. Exclusive catalysis: Iron- and-manganese-based catalysts selectively functionalize the C(sp2)-H bonds of benzene or alkylbenzenes through the formal insertion of the CHCO2Et group from N2CHCO2Et (see scheme). When using alkylbenzenes, the alkylic C(sp3)-H bonds of the substituents remain unmodifiedSupport for this work was provided by the MINECO (CTQ2014-52769-C3-R-1, CTQ2014-62234-EXP, CTQ2015-70795-P, CTQ2014-54306-P, and CTQ2014-52525P), and the Junta de Andaluc a (P10-FQM-06292)WileyMinisterio de Economía y Competitividad (Espanya)2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/13145http://hdl.handle.net/10256/13145© Angewandte Chemie International Edition, 2016, vol. 55, núm. 22, p. 6530-6534Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201601750info:eu-repo/semantics/altIdentifier/issn/1433-7851info:eu-repo/semantics/altIdentifier/eissn/1521-3773info:eu-repo/grantAgreement/MINECO//CTQ2014-54306-Pinfo:eu-repo/grantAgreement/MINECO//CTQ2014-52525-Pinfo:eu-repo/grantAgreement/MINECO//CTQ2015-70795-Pinfo:eu-repo/grantAgreement/EC/FP7/239910Tots els drets reservatsinfo:eu-repo/semantics/openAccessoai:recercat.cat:10256/131452026-05-29T05:05:01Z
dc.title.none.fl_str_mv Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
title Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
spellingShingle Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
Conde Fernández, Ana
Catalitzadors
Catalysts
title_short Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
title_full Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
title_fullStr Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
title_full_unstemmed Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
title_sort Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)-H Bonds by Carbene Insertion
dc.creator.none.fl_str_mv Conde Fernández, Ana
Sabeña Vila, Gerard
Rodríguez Serrat, Mònica
Postils Ribó, Verònica
Luis Luis, Josep Maria
Díaz Requejo, M. Mar
Costas Salgueiro, Miquel
Pérez, Pedro J.
author Conde Fernández, Ana
author_facet Conde Fernández, Ana
Sabeña Vila, Gerard
Rodríguez Serrat, Mònica
Postils Ribó, Verònica
Luis Luis, Josep Maria
Díaz Requejo, M. Mar
Costas Salgueiro, Miquel
Pérez, Pedro J.
author_role author
author2 Sabeña Vila, Gerard
Rodríguez Serrat, Mònica
Postils Ribó, Verònica
Luis Luis, Josep Maria
Díaz Requejo, M. Mar
Costas Salgueiro, Miquel
Pérez, Pedro J.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (Espanya)
dc.subject.none.fl_str_mv Catalitzadors
Catalysts
topic Catalitzadors
Catalysts
description El mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2016, vol. 128, núm. 22, p.6640–6644. DOI http://dx.doi.org/10.1002/ange.201601750
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
peer-reviewed
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/13145
http://hdl.handle.net/10256/13145
url http://hdl.handle.net/10256/13145
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201601750
info:eu-repo/semantics/altIdentifier/issn/1433-7851
info:eu-repo/semantics/altIdentifier/eissn/1521-3773
info:eu-repo/grantAgreement/MINECO//CTQ2014-54306-P
info:eu-repo/grantAgreement/MINECO//CTQ2014-52525-P
info:eu-repo/grantAgreement/MINECO//CTQ2015-70795-P
info:eu-repo/grantAgreement/EC/FP7/239910
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv © Angewandte Chemie International Edition, 2016, vol. 55, núm. 22, p. 6530-6534
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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