Extraordinary mechanical performance in disentangled UHMWPE films processed by compression molding

An approach to obtain disentangled ultra-high molecular weight polyethylene (UHMWPE) films is proposed using a common compression molding. For that, disentangled UHMWPE nascent powders from reactor are processed at temperatures lower than the main melting peak and at high pressure. Then, disentangle...

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Detalles Bibliográficos
Autores: Ferreira, A. E., Ribeiro, M. R., Cramail, H., Lourenço, J. P., Lorenzo, Vicente, Pérez, Ernesto, Cerrada, María L.
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/173876
Acceso en línea:http://hdl.handle.net/10261/173876
Access Level:acceso abierto
Palabra clave:Crystallinity
UHMWPE
Disentangled chains
Indentation modulus
SBA-15 particles
Descripción
Sumario:An approach to obtain disentangled ultra-high molecular weight polyethylene (UHMWPE) films is proposed using a common compression molding. For that, disentangled UHMWPE nascent powders from reactor are processed at temperatures lower than the main melting peak and at high pressure. Then, disentangled UHMWPE films obtained from homogeneous polymerization powders and from those that incorporate SBA-15 mesoporous silica can be easily achieved by this simple methodology. These disentangled UHMWPE based materials show very high crystallinity and, consequently, outstanding elastic modulus and hardness, both further increasing by presence of mesoporous SBA-15 in the hybrids.