Understanding the Adsorption Capacity for CO2 in Reduced Graphene Oxide (rGO) and Modified Ones with Different Heteroatoms in Relation to Surface and Textural Characteristics

Reduced graphene oxide is a material that has a variety of applications, especially in CO2 adsorption. The study of this research is the preparation of reduced graphene oxide with different heteroatoms and how the adsorption capacity is changed. The functionalization with other compounds bearing Si,...

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Detalles Bibliográficos
Autores: Politakos, Nikolaos, Cordero Lanzac, Tomás, Tomovska, Radmila
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/53655
Acceso en línea:http://hdl.handle.net/10810/53655
Access Level:acceso abierto
Palabra clave:reduced graphene oxide
CO2 adsorption
monolith
functionalization
heteroatoms
SEM
solid C-NMR
Descripción
Sumario:Reduced graphene oxide is a material that has a variety of applications, especially in CO2 adsorption. The study of this research is the preparation of reduced graphene oxide with different heteroatoms and how the adsorption capacity is changed. The functionalization with other compounds bearing Si, S, N, and O was before reducing graphene oxide. Different monoliths were prepared by changing the ascorbic acid analogy and the temperature of reduction. The different porosity values, percentages of heteroatoms, and synthetic parameters show that the adsorption capacity is a complex procedure that can be affected by multiple parameters. Microporosity, different functionalities from heteroatoms, and high surface/volume of pores are the significant parameters that affect adsorption. All parameters should establish a balance among all parameters to achieve high adsorption of CO2.