The dynamic kinetic Pd0-catalyzed alkynylation of racemic heterobiaryl sulfonates was used for the asymmetric synthesis of axially chiral heterobiaryl alkynes with a broad scope. The use of Pd(OAc)2/(S)-QUINAP as the precatalyst provides products in excellent yields and enantioselectivities under mi...
Detalhes bibliográficos
| Autores: |
Hornillos, Valentín,
Ros, Abel,
Ramírez-López, Pedro,
Iglesias-Sigüenza, Javier,
Fernández, Rosario,
Lassaletta, José M. |
|---|
| Tipo de documento: | artigo
|
|---|
| Estado: | Versão publicada |
|---|
| Data de publicação: | 2016 |
|---|
| País: | España |
|---|
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
|---|
| Repositório: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
|---|
| OAI Identifier: | oai:digital.csic.es:10261/141903 |
|---|
| Acesso em linha: | http://hdl.handle.net/10261/141903
|
|---|
| Access Level: | Acceso aberto |
|---|
