Intermatrix synthesis as a rapid, inexpensive and reproducible methodology for the in situ functionalization of nanostructured surfaces with Quantum Dots

Intermatrix Synthesis (IMS) technique has proven to be a valid methodology for the in situ incorporation of quantum dots (QDs) in a wide range of nanostructured surfaces for the preparation of advanced hybrid-nanomaterials. In this sense, this communication reports the recent advances in the applica...

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Detalles Bibliográficos
Autores: Bastos Arrieta, Julio Alonso|||0000-0002-8939-6253, Muñoz, Jose, Stenbock-Fermor, Anja, Muñoz, Maria, Muraviev, Dmitri, Céspedes, Francisco, Tsarkova, Larisa A., Baeza, Mireia
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/82484
Acceso en línea:https://hdl.handle.net/2117/82484
https://dx.doi.org/10.1016/j.apsusc.2016.01.277
Access Level:acceso abierto
Palabra clave:Nanotubes
Nanodiamonds
Quantum Dots
Intermatrix Synthesis
Polymeric Thin Films
Nanocomposite
Nanotubs
Àrees temàtiques de la UPC::Enginyeria química
Descripción
Sumario:Intermatrix Synthesis (IMS) technique has proven to be a valid methodology for the in situ incorporation of quantum dots (QDs) in a wide range of nanostructured surfaces for the preparation of advanced hybrid-nanomaterials. In this sense, this communication reports the recent advances in the application of IMS for the synthesis of CdS-QDs with favourable distribution on sulfonated polyetherether ketone (SPEEK) membrane thin films (TFs), Multiwall Carbon Nanotubes (MWCNTs) and Nanodiamonds (NDs). The synthetic route takes advantage of the ion exchange functionality of the reactive surfaces for the loading of the QDs precursor and consequent QDs appearance by precipitation. The benefits of such modified nanomaterials were studied using CdS-QDs@MWCNTs hybrid-nanomaterials. CdS–QDs@MWCNTs has been used as conducting filler for the preparation of electrochemical nanocomposite sensors, which present electrocatalytic properties. Finally, the optical properties of the QDs contained on MWCNTs could allow a new procedure for the analytical detection of nanostructured carbon allotropes in water.