The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3

13 pags., 10 figs., 10 tabs. -- Correction: J. Chem. Phys. 95, 8677 (1991): https://doi.org/10.1063/1.461844

Detalles Bibliográficos
Autores: Fernández Sánchez, José María, Montero, Salvador
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1991
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/271417
Acceso en línea:http://hdl.handle.net/10261/271417
Access Level:acceso abierto
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spelling The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3Fernández Sánchez, José MaríaMontero, Salvador13 pags., 10 figs., 10 tabs. -- Correction: J. Chem. Phys. 95, 8677 (1991): https://doi.org/10.1063/1.461844The torsional Raman spectra of one-conformer partially deuterated derivatives of ethane, CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3 have been experimentally investigated with an improved conventional Raman spectrometer. The recorded spectra have been interpreted with a rotational-torsional effective Hamiltonian and a simple model for the torsional dependence of the molecular polarizability. The effective threefold torsional potential parameters for CH3CD3 (V3 = 997.72 cm-1, V6 = 8.45 cm-1) have been taken from the recent literature, whilst the following parameters were obtained for the other derivatives: CH3CH2D, V 3 = 1007 cm-1, V6 = 7.3 cm-1; CH3CHD2, V3 = 1003 cm-1, V 6 = 8.5 cm-1; CH2DCD3, V3 = 993 cm-1, V6 = 8.2 cm-1; CHD 2CD3, V3 = 995 cm-1, V6 = 6.7 cm-1. The estimated accuracy of these parameters is of the order of ±2 cm-1. © 1991 American Institute of Physics.One of us (J.M.F.) thanks Ministerio de Educación y Ciencia of Spain for a grant of the FPI Program. Thanks are due to the Stiftung Volkswagenwerk of the Federal Republic of Germany for providing the high power laser used in the present work.American Institute of PhysicsMinisterio de Educación y Ciencia (España)Volkswagen FoundationConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2022202219912022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/271417reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1063/1.460165Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2714172026-05-22T06:33:51Z
dc.title.none.fl_str_mv The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
title The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
spellingShingle The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
Fernández Sánchez, José María
title_short The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
title_full The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
title_fullStr The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
title_full_unstemmed The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
title_sort The torsional Raman spectra of partially deuterated ethane molecules. I. One conformer derivatives: CH3CD3, CH3CH 2D, CH3CHD2, CH2DCD3, and CHD2CD3
dc.creator.none.fl_str_mv Fernández Sánchez, José María
Montero, Salvador
author Fernández Sánchez, José María
author_facet Fernández Sánchez, José María
Montero, Salvador
author_role author
author2 Montero, Salvador
author2_role author
dc.contributor.none.fl_str_mv Ministerio de Educación y Ciencia (España)
Volkswagen Foundation
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description 13 pags., 10 figs., 10 tabs. -- Correction: J. Chem. Phys. 95, 8677 (1991): https://doi.org/10.1063/1.461844
publishDate 1991
dc.date.none.fl_str_mv 1991
2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/271417
url http://hdl.handle.net/10261/271417
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://dx.doi.org/10.1063/1.460165
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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score 15.812455

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