Optoelectronic properties of GaP:Ti photovoltaic devices

Supersaturated GaP is of interest for the photovoltaic field since optical transitions at energies below the bandgap (2.26 eV) could enhance the overall device efficiency up to theoretically 60%. We have previously demonstrated that Ti supersaturated GaP can be obtained by means of ion implantation...

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Detalles Bibliográficos
Autores: Olea, Javier, Gonzalo, Jose, Siegel, Jan, Braña de Cal, Alejandro Francisco, Godoy Pérez, Guillermo, Benítez Fernández, Rafael, Caudevilla, D., Algaidy, Sari, Pérez Zenteno, Francisco José, Duarte Cano, Sebastián, Prado, A. del, García Hemme, Eric, García Hernansanz, R., Pastor, David, San Andrés, E., Mártil, Ignacio
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/718441
Acceso en línea:http://hdl.handle.net/10486/718441
https://dx.doi.org/10.1016/j.mtsust.2024.101008
Access Level:acceso abierto
Palabra clave:Optoelectronic devices
photovoltaic effects
Física
Descripción
Sumario:Supersaturated GaP is of interest for the photovoltaic field since optical transitions at energies below the bandgap (2.26 eV) could enhance the overall device efficiency up to theoretically 60%. We have previously demonstrated that Ti supersaturated GaP can be obtained by means of ion implantation and pulsed-laser melting with high structural quality and measured its below-bandgap photoconductivity. In this work we report the first results of a GaP:Ti based photovoltaic device. We have fabricated and measured photovoltaic devices with a GaP:Ti absorber layer showing enhanced external quantum efficiency at wavelengths above 550 nm. Also, we have measured the absorption coefficient (around 104 cm−1) and refractive index of this absorber layer. Finally, current-voltage curves in darkness were measured and analyzed using a two-diodes model, showing improvable characteristics. Ideas to enhance the properties of the devices are suggested