All nanocarbon Li-Ion capacitor with high energy and high power density

An energy storage device reaching energy densities of 102 Wh/Kg at power densities of 10 W/Kg would mean the possibility of charging such a device in 36 s. The nanocarbon device presented here is closer to that feat than any previously reported system. N-doped Carbon Nanopipes were used as anode and...

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Detalhes bibliográficos
Autores: Dubal, Deepak P.|||0000-0002-2337-676X, Gómez-Romero, Pedro|||0000-0002-6208-5340
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:220650
Acesso em linha:https://ddd.uab.cat/record/220650
https://dx.doi.org/urn:doi:10.1016/j.mtener.2018.03.005
Access Level:acceso abierto
Palavra-chave:All nanocarbon
Li-ion capacitor
High energy density
Descrição
Resumo:An energy storage device reaching energy densities of 102 Wh/Kg at power densities of 10 W/Kg would mean the possibility of charging such a device in 36 s. The nanocarbon device presented here is closer to that feat than any previously reported system. N-doped Carbon Nanopipes were used as anode and Partially Reduced Graphene Oxide as cathode, with LiPF EC/PC electrolyte. This system yields simultaneously high energy and power densities (262 at 450 W/kg and 78 Wh/kg at 9000 W/kg) which are energy/power combinations considerably higher than those of present Li-ion batteries. Our cell exhibits excellent cycle stability (∼91% capacity retention after 4000 cycles "0.01-4 V"). These breakthrough results are based on the kinetic balancing of the nanocarbon electrodes, which can deliver excellent high energy density at high rates and low costs.