Nerve agent simulant detection by using chromogenic triaryl methane cation probes

Two triaryl methane cations have been used as probes for colorimetric detection of nerve agent simulants. Buffered mixed aqueous solutions of 1 and 2 showed bathochromic shifts in the presence of DCNP (diethylcyanophosphonate) and DCP (diethylchlorophosphate). The colour modulation can be observed t...

ver descrição completa

Detalhes bibliográficos
Autores: Gotor Candel, Raul Jesús, Royo Calvo, Santiago, Costero Nieto, Ana María, Parra Álvarez, Margarita, Gil Grau, Salvador, Martínez-Máñez, Ramón|||0000-0001-5873-9674, Sancenón Galarza, Félix|||0000-0002-5205-7135
Tipo de documento: artigo
Data de publicação:2012
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:riunet.upv.es:10251/37849
Acesso em linha:https://riunet.upv.es/handle/10251/37849
Access Level:Acceso aberto
Palavra-chave:Chemical warfare
Chemosensor
Chromogenic
Triaryl methane dye
Chemical warfare agent
Triaryl methane cation
Unclassified drug
Aqueous solution
Colorimetry
QUIMICA INORGANICA
QUIMICA ORGANICA
Descrição
Resumo:Two triaryl methane cations have been used as probes for colorimetric detection of nerve agent simulants. Buffered mixed aqueous solutions of 1 and 2 showed bathochromic shifts in the presence of DCNP (diethylcyanophosphonate) and DCP (diethylchlorophosphate). The colour modulation can be observed to the naked eye. Appropriate mechanisms for the recognition event are proposed. © 2012 Elsevier Ltd.