Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes

14 Pág. Centro de Investigación Forestal (CIFOR)

Detalles Bibliográficos
Autores: Yuliestyan, Avido, Partal, Pedro, Navarro, Francisco J., Martín-Sampedro, Raquel, Ibarra, David, Eugenio, María E.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:dnet:digitalcsic_::a977d1069ded88736ab6e12a543a89bb
Acceso en línea:http://hdl.handle.net/10261/278958
Access Level:acceso abierto
Palabra clave:Lignin
Amination
Emulsion
Bitumen
Rheology
Microstructure
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spelling Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping ProcessesYuliestyan, AvidoPartal, PedroNavarro, Francisco J.Martín-Sampedro, RaquelIbarra, DavidEugenio, María E.LigninAminationEmulsionBitumenRheologyMicrostructure14 Pág. Centro de Investigación Forestal (CIFOR)Oil-in-water bitumen emulsions stabilized by biobased surfactants such as lignin are in line with the current sustainable approaches of the asphalt industry involving bitumen emulsions for reduced temperature asphalt technologies. With this aim, three lignins, derived from the kraft pulping and bioethanol industries, were chemically modified via the Mannich reaction to be used as cationic emulsifiers. A comprehensive chemical characterization was conducted on raw lignin-rich products, showing that the kraft sample presents a higher lignin concentration and lower molecular weight. Instead, bioethanol-derived samples, with characteristics of non-woody lignins, present a high concentration of carbohydrate residues and ashes. Lignin amination was performed at pH = 10 and 13, using tetraethylene pentamine and formaldehyde as reagents at three different stoichiometric molar ratios. The emulsification ability of such cationic surfactants was firstly studied on prototype silicone oil-in-water emulsions, attending to their droplet size distribution and viscous behavior. Among the synthetized surfactants, cationic kraft lignin has shown the best emulsification performance, being used for the development of bitumen emulsions. In this regard, cationic kraft lignin has successfully stabilized oil-in-water emulsions containing 60% bitumen using small surfactant concentrations, between 0.25 and 0.75%, which was obtained at pH = 13 and reagent molar ratios between 1/7/7 and 1/28/28 (lignin/tetraethylene pentamine/formaldehyde).This research is part of SUP&R ITN (FP7-PEOPLE-2013-ITN, Grant agreement 607524) and GreenAsphalt project (ref. 802C1800001) co-funded 80% by FEDER European Programme and 20% by Junta de Andalucía (Consejería de Economía, Conocimiento, Empresas y Unversidades/Agencia IDEA). The authors also wish to thank Comunidad de Madrid and MCIU/AEI/FEDER, UE via grant number SUSTEC-CM S2018/EMT-4348 and RTI2018-096080-B-C22, respectively. The contribution of COST Action LignoCOST (CA17128), supported by COST (European Cooperation in Science and Technology), in promoting the interaction, exchange of knowledge and collaborations in the field of lignin valorization is gratefully acknowledged.Peer reviewedMultidisciplinary Digital Publishing InstituteEuropean CommissionJunta de AndalucíaComunidad de MadridYuliestyan, Avido [0000-0002-0300-3229]Partal, Pedro [0000-0003-0141-0733]Navarro, Francisco J.[0000-0002-8277-1073]Martín-Sampedro, Raquel [0000-0003-2083-3723]Ibarra Trejo, David [0000-0003-3001-7308]Eugenio, María E. [0000-0003-4550-5400]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/278958reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC//607524S2018/EMT-4348/SUSTEC-CMinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-096080-B-C22https://doi.org/10.3390/polym14142879Síinfo:eu-repo/semantics/openAccessoai:dnet:digitalcsic_::a977d1069ded88736ab6e12a543a89bb2026-05-22T06:33:51Z
dc.title.none.fl_str_mv Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
title Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
spellingShingle Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
Yuliestyan, Avido
Lignin
Amination
Emulsion
Bitumen
Rheology
Microstructure
title_short Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
title_full Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
title_fullStr Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
title_full_unstemmed Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
title_sort Emulsion Stabilization by Cationic Lignin Surfactants Derived from Bioethanol Production and Kraft Pulping Processes
dc.creator.none.fl_str_mv Yuliestyan, Avido
Partal, Pedro
Navarro, Francisco J.
Martín-Sampedro, Raquel
Ibarra, David
Eugenio, María E.
author Yuliestyan, Avido
author_facet Yuliestyan, Avido
Partal, Pedro
Navarro, Francisco J.
Martín-Sampedro, Raquel
Ibarra, David
Eugenio, María E.
author_role author
author2 Partal, Pedro
Navarro, Francisco J.
Martín-Sampedro, Raquel
Ibarra, David
Eugenio, María E.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Junta de Andalucía
Comunidad de Madrid
Yuliestyan, Avido [0000-0002-0300-3229]
Partal, Pedro [0000-0003-0141-0733]
Navarro, Francisco J.[0000-0002-8277-1073]
Martín-Sampedro, Raquel [0000-0003-2083-3723]
Ibarra Trejo, David [0000-0003-3001-7308]
Eugenio, María E. [0000-0003-4550-5400]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Lignin
Amination
Emulsion
Bitumen
Rheology
Microstructure
topic Lignin
Amination
Emulsion
Bitumen
Rheology
Microstructure
description 14 Pág. Centro de Investigación Forestal (CIFOR)
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/278958
url http://hdl.handle.net/10261/278958
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC//607524
S2018/EMT-4348/SUSTEC-CM
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-096080-B-C22
https://doi.org/10.3390/polym14142879
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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