The two alternative rate-determining steps in benzylic lithiation reactions of esters and Carbamates
Lithiation reactions of tertiary benzylic esters and carbamates have been studied. Kinetic methodology revealed that a two-step reaction pathway should be considered for these reactions, where either the lithium precomplexation and/or the proton transfer steps can be rate determining. Kinetic isotop...
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Detalhes bibliográficos
| Autores: |
Fernández-Nieto, Fernando,
Paleo Pillado, María Rita,
Colunga Seara, Roberto,
Raposo, María Luz,
García Río, Luis,
Sardina López, Francisco Javier |
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| Formato: | artículo
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| Fecha de publicación: | 2016 |
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| País: | España |
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| Recursos: | Universidad de Santiago de Compostela (USC) |
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| Repositorio: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
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| Idioma: | inglés |
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| OAI Identifier: | oai:minerva.usc.gal:10347/32250 |
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| Acesso em linha: | http://hdl.handle.net/10347/32250
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| Access Level: | acceso abierto |
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| Palavra-chave: | 2306 Química orgánica |
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