Picking the lock of coordination cage catalysis
[EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the acti...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | inglés |
| OAI Identifier: | oai:riunet.upv.es:10251/209239 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/209239 |
| Access Level: | acceso abierto |
| Palabra clave: | Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
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Picking the lock of coordination cage catalysisPiskorz, Tomasz K.Spicer, RebeccaDuarte, FernandaLusby, Paul J.Martí-Centelles, Vicente|||0000-0002-9142-9392Metallo-organic assembly reactionsCatalysisCoordination cagesNon-covalent catalysisQUIMICA INORGANICA[EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the active site of an enzyme. While there are now a growing collection of coordination cages that show highly proficient catalysis, exhibiting both excellent activity and efficient turnover, this number is still small compared to the vast library of metal¿organic structures that are known. In this review, we will attempt to unpick and discuss the key features that make an effective coordination cage catalyst, linking structure to activity (and selectivity) using lessons learnt from both experimental and computational analysis of the most notable exemplars. We will also provide an outlook for this area, reasoning why coordination cages have the potential to become the gold-standard in (synthetic) non-covalent catalysis.T. K. P., P. J. L., and F. D. acknowledge the nancial support from EPSRC (EP/W010666/1 and EP/W009803/1). V. M.-C.acknowledges the nancial support from Generalitat Valenciana (CIDEGENT/2020/031).The Royal Society of ChemistryEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialDepartamento de QuímicaInstituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo TecnológicoGENERALITAT VALENCIANAEngineering and Physical Sciences Research Council, Reino UnidoRepositorio Institucional de la Universitat Politècnica de València Riunet20232023-10-25journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/209239reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengGeneralitat Valenciana https://doi.org/10.13039/501100003359 CIDEGENT%2F2020%2F031 AYUDA CONTRATO CIDEGENT-MARTI CENTELLESGeneralitat Valenciana https://doi.org/10.13039/501100003359 CIDEGENT%2F2020%2F031 CAJAS ORGANICAS COMO CONTENEDORES PARA LIBERACION DIRIGIDA DE FARMACOS EN TERAPIA CONTRA EL CANCEREngineering and Physical Sciences Research Council, Reino Unido https://doi.org/10.13039/501100000266 EP%2FW009803%2F1Engineering and Physical Sciences Research Council, Reino Unido https://doi.org/10.13039/501100000266 EP%2FW010666%2F1open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2092392026-06-13T07:49:27Z |
| dc.title.none.fl_str_mv |
Picking the lock of coordination cage catalysis |
| title |
Picking the lock of coordination cage catalysis |
| spellingShingle |
Picking the lock of coordination cage catalysis Piskorz, Tomasz K. Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| title_short |
Picking the lock of coordination cage catalysis |
| title_full |
Picking the lock of coordination cage catalysis |
| title_fullStr |
Picking the lock of coordination cage catalysis |
| title_full_unstemmed |
Picking the lock of coordination cage catalysis |
| title_sort |
Picking the lock of coordination cage catalysis |
| dc.creator.none.fl_str_mv |
Piskorz, Tomasz K. Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 |
| author |
Piskorz, Tomasz K. |
| author_facet |
Piskorz, Tomasz K. Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 |
| author_role |
author |
| author2 |
Spicer, Rebecca Duarte, Fernanda Lusby, Paul J. Martí-Centelles, Vicente|||0000-0002-9142-9392 |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial Departamento de Química Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico GENERALITAT VALENCIANA Engineering and Physical Sciences Research Council, Reino Unido Repositorio Institucional de la Universitat Politècnica de València Riunet |
| dc.subject.none.fl_str_mv |
Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| topic |
Metallo-organic assembly reactions Catalysis Coordination cages Non-covalent catalysis QUIMICA INORGANICA |
| description |
[EN] The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the active site of an enzyme. While there are now a growing collection of coordination cages that show highly proficient catalysis, exhibiting both excellent activity and efficient turnover, this number is still small compared to the vast library of metal¿organic structures that are known. In this review, we will attempt to unpick and discuss the key features that make an effective coordination cage catalyst, linking structure to activity (and selectivity) using lessons learnt from both experimental and computational analysis of the most notable exemplars. We will also provide an outlook for this area, reasoning why coordination cages have the potential to become the gold-standard in (synthetic) non-covalent catalysis. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2023-10-25 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 VoR http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://riunet.upv.es/handle/10251/209239 |
| url |
https://riunet.upv.es/handle/10251/209239 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.relation.none.fl_str_mv |
Generalitat Valenciana https://doi.org/10.13039/501100003359 CIDEGENT%2F2020%2F031 AYUDA CONTRATO CIDEGENT-MARTI CENTELLES Generalitat Valenciana https://doi.org/10.13039/501100003359 CIDEGENT%2F2020%2F031 CAJAS ORGANICAS COMO CONTENEDORES PARA LIBERACION DIRIGIDA DE FARMACOS EN TERAPIA CONTRA EL CANCER Engineering and Physical Sciences Research Council, Reino Unido https://doi.org/10.13039/501100000266 EP%2FW009803%2F1 Engineering and Physical Sciences Research Council, Reino Unido https://doi.org/10.13039/501100000266 EP%2FW010666%2F1 |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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open access http://purl.org/coar/access_right/c_abf2 Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/ |
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openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
The Royal Society of Chemistry |
| publisher.none.fl_str_mv |
The Royal Society of Chemistry |
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reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia instname:Universitat Politècnica de València (UPV) |
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