Retention of pesticides in soil columns modified "in situ" and "ex situ" with a cationic surfactant

A study of the effect of a clayey soil modified in situ and ex situ with the cationic surfactant octadecyltrimethylammonium bromide (ODTMA), on the retention of linuron, atrazine and metalaxyl was carried out. Leaching of these compounds was studied in columns of a natural clayey soil and the same c...

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Detalles Bibliográficos
Autores: Rodríguez-Cruz, M.S. [0000-0001-6748-3391], Sánchez-Martín, M.J. [0000-0002-8304-1232], Andrades, M.S. [0000-0003-4136-8656], Sánchez-Camazano, M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2007
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc688bb750603269e80acd
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc688bb750603269e80acd
Access Level:acceso abierto
Palabra clave:Barriers
Cationic surfactant
Immobilization
Pesticides
Soils
Descripción
Sumario:A study of the effect of a clayey soil modified in situ and ex situ with the cationic surfactant octadecyltrimethylammonium bromide (ODTMA), on the retention of linuron, atrazine and metalaxyl was carried out. Leaching of these compounds was studied in columns of a natural clayey soil and the same clayey soil modified by direct injection of the surfactant in situ, and in columns of a natural sandy soil and the same sandy soil modified by intercalation of a barrier of the clayey soil saturated ex situ with the surfactant. Breakthrough curves indicated the total immobilization of linuron in modified soils and a decrease in the leaching kinetics of atrazine and metalaxyl compared to what was obtained in the natural soil. The results indicate the use of the clayey soil modified in situ or ex situ with the surfactant ODTMA could be of interest in the immobilization of pesticides of different hydrophobicities. © 2007 Elsevier B.V. All rights reserved.