Forging C–C Bonds Through Decarbonylation of Aryl Ketones
The ability of nickel to cleave strong σ‐bonds is again in the spotlight after a recent report that demonstrates the feasibility of using nickel complexes to promote decarbonylation of diaryl ketones. This transformation involves the cleavage of two strong C−C(O) bonds and avoids the use of noble me...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2017 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/335527 |
| Acceso en línea: | http://hdl.handle.net/2072/335527 https://doi.org/10.1002/anie.201702188 |
| Access Level: | acceso abierto |
| Palabra clave: | 54 |
| Sumario: | The ability of nickel to cleave strong σ‐bonds is again in the spotlight after a recent report that demonstrates the feasibility of using nickel complexes to promote decarbonylation of diaryl ketones. This transformation involves the cleavage of two strong C−C(O) bonds and avoids the use of noble metals, hence reinforcing the potential of decarbonylation as a technique for forging C−C bonds. |
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