Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)

<p>While many photoresponsive metal‒organic frameworks (MOFs) have been reported to date, finding applications in several technologically relevant fields such as photocatalysis, sensors, and light-emitting devices, significantly scarcer are the reports addressing the relationship between the M...

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Detalles Bibliográficos
Autores: Romero-Muñiz, Ignacio, García Calvo, José, Romero-Muñiz, Carlos, Torres, Tomás, Zamora, Félix, Bottari, Giovanni
Tipo de recurso: conjunto de datos
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consorcio Madroño
Repositorio:e-cienciaDatos, Repositorio de Datos del Consorcio Madroño
OAI Identifier:doi:10.21950/P1VLQ2
Acceso en línea:https://doi.org/10.21950/P1VLQ2
Access Level:acceso abierto
Palabra clave:Chemistry
Confocal Fluorescence Microscopy
Fluorescence Lifetime Imaging Microscopy
Perylenes
Zr-MOFs
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spelling Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)Romero-Muñiz, IgnacioGarcía Calvo, JoséRomero-Muñiz, CarlosTorres, TomásZamora, FélixBottari, GiovanniChemistryConfocal Fluorescence MicroscopyFluorescence Lifetime Imaging MicroscopyPerylenesZr-MOFs<p>While many photoresponsive metal‒organic frameworks (MOFs) have been reported to date, finding applications in several technologically relevant fields such as photocatalysis, sensors, and light-emitting devices, significantly scarcer are the reports addressing the relationship between the MOFs emissive features and their crystalline domain size (i.e., micro- and nano-sized materials). Herein, a valuable contribution is offered to this issue which consists of the use of reticular chemistry to prepare a Zr-MOF featuring spatially separated tetracarboxylated-functionalized perylenes as ligand. Single crystal X-ray analysis of such Zr-MOF revealed the formation of micro- and meso-porous channels. The perylene-based Zr-MOF exhibited notable optoelectronic features, including a relatively small optical bandgap of 1.82 eV and emission features different from that of the constituting perylene ligand in the solid state. Additionally, local probe techniques are used to unveil the emission properties of isolated Zr-MOF crystals. Space- and time-resolved fluorescence studies revealed a strong dependence of the emissive features of the Zr-MOF, both in terms of its intensity and lifetime, to the crystalline domain size.</p> <p>Characterization of compounds (Raw data). Supplementary material of the paper published in doi:10.1002/adom.202402127</p>e-cienciaDatosRomero-Muñiz, Ignacio2024info:eu-repo/semantics/datasetinfo:eu-repo/semantics/publishedVersionapplication/octet-streamapplication/zipapplication/ziptext/plainapplication/zipapplication/zipapplication/ziphttps://doi.org/10.21950/P1VLQ2reponame:e-cienciaDatos, Repositorio de Datos del Consorcio Madroñoinstname:Consorcio MadroñoInglésinfo:eu-repo/grantAgreement/AEI//PID2020-116490GB-I00info:eu-repo/grantAgreement/AEI//PID2023-151167NB-I00info:eu-repo/grantAgreement/Comunidad de Madrid/S2013%2FMIT-3007-MAD2D/info:eu-repo/grantAgreement/AEI//SEV-2016-0686info:eu-repo/grantAgreement/AEI//CEX2020-001039-Sinfo:eu-repo/grantAgreement/AEI//RYC2021-031176-Iinfo:eu-repo/grantAgreement/Comunidad de Madrid/2022- T1%2FIND23907/info:eu-repo/grantAgreement/Ministerio de Ciencia, Innovación y Universidades/CA3%2FRSUE%2F 2021-00243/info:eu-repo/semantics/openAccessCC-BY-4.0doi:10.21950/P1VLQ22026-05-29T06:25:11Z
dc.title.none.fl_str_mv Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
title Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
spellingShingle Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
Romero-Muñiz, Ignacio
Chemistry
Confocal Fluorescence Microscopy
Fluorescence Lifetime Imaging Microscopy
Perylenes
Zr-MOFs
title_short Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
title_full Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
title_fullStr Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
title_full_unstemmed Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
title_sort Space- and time-resolved emission features of micro- and nano-sized perylene-based Zr metal-organic frameworks (dataset)
dc.creator.none.fl_str_mv Romero-Muñiz, Ignacio
García Calvo, José
Romero-Muñiz, Carlos
Torres, Tomás
Zamora, Félix
Bottari, Giovanni
author Romero-Muñiz, Ignacio
author_facet Romero-Muñiz, Ignacio
García Calvo, José
Romero-Muñiz, Carlos
Torres, Tomás
Zamora, Félix
Bottari, Giovanni
author_role author
author2 García Calvo, José
Romero-Muñiz, Carlos
Torres, Tomás
Zamora, Félix
Bottari, Giovanni
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Romero-Muñiz, Ignacio
dc.subject.none.fl_str_mv Chemistry
Confocal Fluorescence Microscopy
Fluorescence Lifetime Imaging Microscopy
Perylenes
Zr-MOFs
topic Chemistry
Confocal Fluorescence Microscopy
Fluorescence Lifetime Imaging Microscopy
Perylenes
Zr-MOFs
description <p>While many photoresponsive metal‒organic frameworks (MOFs) have been reported to date, finding applications in several technologically relevant fields such as photocatalysis, sensors, and light-emitting devices, significantly scarcer are the reports addressing the relationship between the MOFs emissive features and their crystalline domain size (i.e., micro- and nano-sized materials). Herein, a valuable contribution is offered to this issue which consists of the use of reticular chemistry to prepare a Zr-MOF featuring spatially separated tetracarboxylated-functionalized perylenes as ligand. Single crystal X-ray analysis of such Zr-MOF revealed the formation of micro- and meso-porous channels. The perylene-based Zr-MOF exhibited notable optoelectronic features, including a relatively small optical bandgap of 1.82 eV and emission features different from that of the constituting perylene ligand in the solid state. Additionally, local probe techniques are used to unveil the emission properties of isolated Zr-MOF crystals. Space- and time-resolved fluorescence studies revealed a strong dependence of the emissive features of the Zr-MOF, both in terms of its intensity and lifetime, to the crystalline domain size.</p> <p>Characterization of compounds (Raw data). Supplementary material of the paper published in doi:10.1002/adom.202402127</p>
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/dataset
info:eu-repo/semantics/publishedVersion
format dataset
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.21950/P1VLQ2
url https://doi.org/10.21950/P1VLQ2
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/AEI//PID2020-116490GB-I00
info:eu-repo/grantAgreement/AEI//PID2023-151167NB-I00
info:eu-repo/grantAgreement/Comunidad de Madrid/S2013%2FMIT-3007-MAD2D/
info:eu-repo/grantAgreement/AEI//SEV-2016-0686
info:eu-repo/grantAgreement/AEI//CEX2020-001039-S
info:eu-repo/grantAgreement/AEI//RYC2021-031176-I
info:eu-repo/grantAgreement/Comunidad de Madrid/2022- T1%2FIND23907/
info:eu-repo/grantAgreement/Ministerio de Ciencia, Innovación y Universidades/CA3%2FRSUE%2F 2021-00243/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
CC-BY-4.0
eu_rights_str_mv openAccess
rights_invalid_str_mv CC-BY-4.0
dc.format.none.fl_str_mv application/octet-stream
application/zip
application/zip
text/plain
application/zip
application/zip
application/zip
dc.publisher.none.fl_str_mv e-cienciaDatos
publisher.none.fl_str_mv e-cienciaDatos
dc.source.none.fl_str_mv reponame:e-cienciaDatos, Repositorio de Datos del Consorcio Madroño
instname:Consorcio Madroño
instname_str Consorcio Madroño
reponame_str e-cienciaDatos, Repositorio de Datos del Consorcio Madroño
collection e-cienciaDatos, Repositorio de Datos del Consorcio Madroño
repository.name.fl_str_mv
repository.mail.fl_str_mv
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