Hydrothermal carbonization vs. anaerobic digestion to valorize fruit and vegetable waste: A comparative technical and energy assessment

[EN] Herein, the valorization of vegetable and fruit waste was assessed via hydrothermal carbonization (HTC) and anaerobic digestion (AD) in terms of product characterization and energy requirements. HTC was conducted at reaction temperatures between 150 ºC and 190 ºC, and residence times between 20...

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Bibliographic Details
Authors: Metyouy, Khadija, González González, Rubén, Gómez Barrios, Xiomar Arleth, González Arias, Judith, Martínez Torres, Elia Judith, Chafik, Tarik, Sánchez Morán, Marta Elena, Cara Jiménez, Jorge
Format: article
Status:Versión aceptada para publicación
Publication Date:2023
Country:España
Institution:Universidad de León
Repository:BULERIA. Repositorio Institucional de la Universidad de León
OAI Identifier:oai:buleria.unileon.es:10612/26704
Online Access:https://hdl.handle.net/10612/26704
Access Level:Open access
Keyword:Ingeniería química
Vegetable and fruit waste (VFW)
Hydrothermal carbonization (HTC)
Hydrochar
Anaerobic digestion (AD)
Energy recovery
3303 Ingeniería y Tecnología Químicas
Description
Summary:[EN] Herein, the valorization of vegetable and fruit waste was assessed via hydrothermal carbonization (HTC) and anaerobic digestion (AD) in terms of product characterization and energy requirements. HTC was conducted at reaction temperatures between 150 ºC and 190 ºC, and residence times between 20 min and 40 min. The increase in the process severity resulted in hydrochars with higher carbon contents and higher energy densification ratios. AD was performed in two different ways. i.e., batch and semi-continuous reactions. From the batch experiments a methane yield of 300 L CH4/kg VS was obtained, while for the semi-continuous, the average specific methane production estimated (for HRTs from 75 to 50 days) was 213 ± 32 L CH4/kg VS. To estimate the energy requirements, mass and energy balances were performed considering the basic stages of each process to obtain a suitable biofuel material. In this sense, it was concluded that for this specific waste, AD was a more suitable process with a positive energy net balance. On the contrary, HTC presented a negative energy net balance being required 1.29 MJ/kg of fresh food waste. A combined HTC-AD treatment may be an efficient method to take advantage of both technologies leading to higher energy efficiencies and other valuable products.