Competition effects during femtosecond laser induced element redistribution in Ba- and La-migration based laser written waveguides

Fs-laser induced element redistribution (FLIER) has been a subject of intensive research in recent years. Its application to various types of glasses has already resulted in the production of efficient optical waveguides, tappers, amplifiers and lasers. Most of the work reported on FLIER-based waveg...

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Detalles Bibliográficos
Autores: Macías Montero, Manuel, Moreno Zárate, Pedro, Muñoz, Francisco, Sotillo Buzarra, Belén, García Pardo, Marina, Serna, Rosalia, Fernández Sánchez, Paloma, Solís, Javier
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/8323
Acceso en línea:https://hdl.handle.net/20.500.14352/8323
Access Level:acceso abierto
Palabra clave:538.9
Ion migration
Electronic polarizability
Photonic devices
Glass
Distributions
Inscription
Fabrication
Fs-laser writing
Waveguides
Element redistribution
Soret effect
Diffusion competition effects
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:Fs-laser induced element redistribution (FLIER) has been a subject of intensive research in recent years. Its application to various types of glasses has already resulted in the production of efficient optical waveguides, tappers, amplifiers and lasers. Most of the work reported on FLIER-based waveguides refers to structures produced by the cross-migration of alkali (Na, K) and lanthanides (mostly La). The latter elements act as refractive index carrying elements. Herein, we report the production of Ba-based, FLIER-waveguides in phosphate glass with an index contrast > 10^(-2). Phosphate glasses modified with the same amount of Na_2O and K_2O, and variable amounts of BaO and/or La_2O_3 were used to produce the FLIER-waveguides with Ba and or La acting as index carriers. Ba-only modified glasses show a waveguide writing threshold and light guiding performance comparable to that of La-based structures. However, mixed Ba-La glasses show a much higher element migration threshold, and much smaller compositionally modified regions. This behavior is consistent with a competition effect in the cross-migration of both elements (Ba and La) against the alkalis. Such an effect can be applied to inhibit undesired element redistribution effects in fs-laser processing applications in multicomponent glasses.