Metal organic frameworks as solid catalysts for liquid-phase continuous flow reactions

[EN] Metal organic frameworks (MOFs) are widely used as solid catalysts in the liquid phase under batch mode conditions. Moving towards the development of industrial processes, data of the performance of MOFs under continuous flow operation would be desirable. This feature article describes the stat...

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Detalles Bibliográficos
Autores: Dhakshinamoorthy, Amarajothi, Asiri, Abdullah M., Navalón Oltra, Sergio|||0000-0001-8423-0759, García Gómez, Hermenegildo|||0000-0002-9664-493X
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/158949
Acceso en línea:https://riunet.upv.es/handle/10251/158949
Access Level:acceso abierto
Palabra clave:QUIMICA ORGANICA
Descripción
Sumario:[EN] Metal organic frameworks (MOFs) are widely used as solid catalysts in the liquid phase under batch mode conditions. Moving towards the development of industrial processes, data of the performance of MOFs under continuous flow operation would be desirable. This feature article describes the state of the art regarding the use of MOFs as catalysts of continuous flow processes, paying special attention to the issue of catalyst stability. The review is organized according to the type of bond that is formed in the reaction from C-C, to C-O to C-N bonds. Examples are presented of MOF catalysts that are stable under continuous flow operation, even for those structures that are not very stable such as Cu-3(BTC)(2). It can be anticipated that there will be a growth in the percentage of studies carried out under continuous flow with the final goal of implementing a commercial chemical process using MOFs as a catalyst.