A First Cyclodextrin-Transition Metal Coordination Polymer
The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu) are shown. This coordination polymer is made by connecting paddle-wheel Cu units through a γ-cyclodextrin functionaliz...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:212933 |
| Acceso en línea: | https://ddd.uab.cat/record/212933 https://dx.doi.org/urn:doi:10.1021/acs.cgd.6b01115 |
| Access Level: | acceso abierto |
| Palabra clave: | Carboxylate groups Coordination Polymers Functionalized Gamma-cyclodextrin Metal-coordination polymer Structural transformation Water-uptake measurements X-ray crystallographic structures |
| Sumario: | The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu) are shown. This coordination polymer is made by connecting paddle-wheel Cu units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations. |
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