Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties

15 páginas, 9 figuras, 4 tablas

Detalles Bibliográficos
Autores: López-Sánchez, Jesús, Peña, Álvaro, Serrano, Aída, Del Campo, Adolfo, Rodríguez de la Fuente, Óscar, Carmona, N., Matatagui, Daniel, Horrillo, Carmen, Rubio-Zuazo, J., Navarro, Elena, Marín, Pilar
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/347927
Acceso en línea:http://hdl.handle.net/10261/347927
Access Level:acceso abierto
Palabra clave:High-energy ball milling
Defective few-layered graphene mesostructures
Confocal Raman microscopy
id ES_1406c1b77d6f8b95cd2c0896fdebb09f
oai_identifier_str oai:digital.csic.es:10261/347927
network_acronym_str ES
network_name_str España
repository_id_str
spelling Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing PropertiesLópez-Sánchez, JesúsPeña, ÁlvaroSerrano, AídaDel Campo, AdolfoRodríguez de la Fuente, ÓscarCarmona, N.Matatagui, DanielHorrillo, CarmenRubio-Zuazo, J.Navarro, ElenaMarín, PilarHigh-energy ball millingDefective few-layered graphene mesostructuresConfocal Raman microscopy15 páginas, 9 figuras, 4 tablasDefective few-layered graphene mesostructures (DFLGMs) are produced from graphite flakes by high-energy milling processes. We obtain an accurate control of the generated mesostructures, as well as of the amount and classification of the structural defects formed, providing a functional material for microwave absorption purposes. Working under far-field conditions, competitive values of minimum reflection loss coefficient (RLmin) = ¿21.76 dB and EAB = 4.77 dB are achieved when DFLGMs are immersed in paints at a low volume fraction (1.95%). One step forward is developed by combining them with the excellent absorption behavior that offers amorphous Fe73.5Si13.5B9Cu1Nb microwires (MWs), varying their filling contents, which are below 3%. We obtain a RLmin improvement of 47% (¿53.08 dB) and an EAB enhancement of 137% (4 dB) compared to those obtained by MW-based paints. Furthermore, a fmin tunability is demonstrated, maintaining similar RLmin and EAB values, irrespective of an ideal matching thickness. In this scenario, the Maxwell-Garnet standard model is valid, and dielectric losses mainly come from multiple reflections, interfacial and dielectric polarizations, which greatly boost the microwave attenuation of MWs. The present concept can remarkably enhance not only the MW attenuation but can also apply to other microwave absorption architectures of technological interest by adding low quantities of DFLGMs.The present work has been supported by the Ministerio Español de Ciencia e Innovación (MICINN) through the projects: PIE-2010-OE-013-200014, PIE 2021-60-E-030, RTI2018-095856-B-C21, and RTI2018-095303-A-C52; Ministerio de Asuntos Económicos y Transformación Digital (MINECO) by PID2020-114192RB-C41; and Comunidad de Madrid, Spain, by S2018/NMT-4321 NANOMAGCOST. MICINN also supports A.S., D.M., and A.P. through the grants RYC2021-031236-I, RYC2021-031166-I, and PRE2019-0875001234, respectivelyPeer reviewedAmerican Chemical SocietyMinisterio de Ciencia e Innovación (España)Ministerio de Asuntos Económicos y Transformación Digital (España)Comunidad de MadridConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420232024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/347927reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095856-B-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095303-A-C52info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-114192RB-C41S2018/NMT-4321/NANOMAGCOSTinfo:eu-repo/grantAgreement/AEI//RYC2021-031236-Iinfo:eu-repo/grantAgreement/AEI//RYC2021-031166-Ihttp://dx.doi.org/10.1021/acsami.2c19886Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3479272026-05-22T06:33:51Z
dc.title.none.fl_str_mv Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
title Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
spellingShingle Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
López-Sánchez, Jesús
High-energy ball milling
Defective few-layered graphene mesostructures
Confocal Raman microscopy
title_short Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
title_full Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
title_fullStr Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
title_full_unstemmed Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
title_sort Generation of Defective Few-Layered Graphene Mesostructures by High-Energy Ball Milling and Their Combination with FeSiCuNbB Microwires for Reinforcing Microwave Absorbing Properties
dc.creator.none.fl_str_mv López-Sánchez, Jesús
Peña, Álvaro
Serrano, Aída
Del Campo, Adolfo
Rodríguez de la Fuente, Óscar
Carmona, N.
Matatagui, Daniel
Horrillo, Carmen
Rubio-Zuazo, J.
Navarro, Elena
Marín, Pilar
author López-Sánchez, Jesús
author_facet López-Sánchez, Jesús
Peña, Álvaro
Serrano, Aída
Del Campo, Adolfo
Rodríguez de la Fuente, Óscar
Carmona, N.
Matatagui, Daniel
Horrillo, Carmen
Rubio-Zuazo, J.
Navarro, Elena
Marín, Pilar
author_role author
author2 Peña, Álvaro
Serrano, Aída
Del Campo, Adolfo
Rodríguez de la Fuente, Óscar
Carmona, N.
Matatagui, Daniel
Horrillo, Carmen
Rubio-Zuazo, J.
Navarro, Elena
Marín, Pilar
author2_role author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Ministerio de Asuntos Económicos y Transformación Digital (España)
Comunidad de Madrid
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv High-energy ball milling
Defective few-layered graphene mesostructures
Confocal Raman microscopy
topic High-energy ball milling
Defective few-layered graphene mesostructures
Confocal Raman microscopy
description 15 páginas, 9 figuras, 4 tablas
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/347927
url http://hdl.handle.net/10261/347927
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095856-B-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095303-A-C52
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-114192RB-C41
S2018/NMT-4321/NANOMAGCOST
info:eu-repo/grantAgreement/AEI//RYC2021-031236-I
info:eu-repo/grantAgreement/AEI//RYC2021-031166-I
http://dx.doi.org/10.1021/acsami.2c19886
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869403712752975872
score 15.812429

Similares en LA Referencia